Steel plate with Young's high modulus and its production process

专利摘要:

公开号:ES2651242T9
申请号:ES07831772.4T
申请日:2007-11-07
公开日:2018-05-30
发明作者:Natsuko Sugiura；Naoki Maruyama；Manabu Takahashi；Yohji Nakamura；Koji Hanya
申请人:Nippon Steel Corp；
IPC主号:

专利说明:

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DESCRIPTION
Steel plate with Young's high module and production process of the same Technical field
The present invention relates to a steel sheet with a high Young's modulus and a method of production thereof.
Background of the invention
The correlation of Young's modulus and the orientation of the iron crystal is extremely strong. For example, Young's module in the orientation of <111> is ideally greater than 280 GPa, while Young's module in an orientation of <110> is approximately 220 GPa. On the other hand, Young's module in an orientation of <100> is approximately 130 GPa. Young's modulus changes according to the crystalline orientation. Moreover, when the crystalline orientation of the steel material does not follow an orientation in any specific direction, that is, the texture is random, Young's modulus of the steel sheet is approximately 205 GPa.
Until now, a large number of technologies have been proposed with respect to steel sheets that control the texture to elevate Young's modulus in a perpendicular direction corresponding to the rolling direction (referred to as the "transverse direction"). In addition, for technology that simultaneously elevates Young's modulus in a rolling direction and in a transverse direction of the steel sheet, for example, Japanese Patent Publication (A) No. 4-147917 proposes a method of production of a steel plate not only in a rolling in a certain direction, but also in a rolling in a direction perpendicular to it. This method of changing the rolling direction in the center can be performed relatively easily in the rolling process of a steel plate.
However, even in the case of production of a steel plate, depending on the width and length of the steel plate, it is sometimes necessary to make the rolling direction fixed. In addition, in particular, in the case of a thin gauge steel sheet, the sheet is usually produced by the continuous hot rolling process consisting of continuously rolling a steel slab to obtain a steel strip, so that the technology that changes the direction of lamination in the center is not practical. In addition, the width of the thin gauge steel sheet produced by the continuous hot rolling process is a maximum of approximately 2 m. For this reason, for example, to apply a sheet of steel with a high Young's modulus to a construction material or to another member longer than 2 m, it was necessary to raise the Young's modulus in the rolling direction.
To meet these requirements, some of the inventors proposed the method of giving a shear deformation to the surface layer of a part of a steel sheet to raise Young's modulus in the direction of lamination of the part of a surface layer (by example, Japanese Patent Publication (A) No. 2005-273001, International Patent Publication No. 06-011503, Japanese Patent Publication (A) No. 200746146 and Japanese Patent Publication (A) No. 2007 -146275).
The steel sheets obtained by the methods proposed in these patent documents have textures that increase Young's modulus in the direction of lamination in the part of a surface layer. For this reason, these steel sheets have high Young modules of the parts of a surface layer and have Young modules measured by the vibration method greater than 230 GPa.
A method of measuring Young's modulus, that is, the vibration method, gives a bending deformation corresponding to a steel sheet while changing the frequency, finds the frequency at which the resonance occurs, and converts it to the module of Young. Young's modulus measured by this method is also called the "dynamic Young's modulus." This is Young's modulus obtained at the time of flexion deformation. The contribution of the part of a surface layer with the moment of wide flexion is enormous.
However, for example, when a load is applied to long beams or columns or other building materials or structural members of automobiles, such as pillars or support members or other long frame elements, the tension acting on these is the tension Tensile and compression tension and not bending tension. In addition, car support members require high impact energy absorption capacity when they receive a compressive deformation from the point of view of impact safety. For this reason, in order to improve the impact energy absorption of the member, it is necessary to ensure stiffness with respect to tensile stress and compression stress. In view of such requirements, it is effective to raise Young's modulus in the longitudinal direction of the member with respect to tensile stress and compression stress.
Therefore, for the Young's modulus of the member to act on this tension of tension and compression tension, it is extremely important to raise the Young's modulus measured not by the vibration method, but by the static tension method, that is, Young's static module. The static Young's module is the
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Young's modulus found in the inclination in the region of elastic deformation of the stress-strain curve obtained at the time of the tensile test. The Young's modulus of the material is determined as a whole solely by the relationship between the thickness of the Young's high modulus layer and the lower layer.
To raise the static Young's modulus in the rolling direction, it is necessary to control the texture of the surface layer corresponding to a deep location in the thickness direction of the sheet. Note that the control of the texture of the entire thickness of the sheet of the surface layer corresponding to the central location of the thickness of the sheet is more preferable.
However, in the method proposed in these patent documents, it was difficult to introduce a shear deformation to the central part corresponding to the thickness of the sheet at the time of lamination. In addition, depending on the ingredients and production conditions, in the texture of the central part corresponding to the thickness of the sheet, there is the possibility of forming an orientation that reduces Young's modulus in the rolling direction.
For this reason, while Young's module measured by the vibration method can be raised to 230 GPa or more, Young's module measured by the static tension method is not necessarily high. That is, a steel sheet with a Young's modulus has never been produced in the rolling direction measured by the static tension method of 220 GPa or more.
European Patent EP 1 806 421 A1 describes a steel sheet with a high Young's modulus, where it has a chemical composition, in mass%, of C: 0.0005 to 0.30%, Si: 2.5% or less, Mn: 2.7 to 5.0%, P: 0.15% or less, S: 0.015% or less, Mo: 0.15 to 1.5%, B: 0.0006 to 0.01% , Al: 0.15% or less, and the rest: Fees and unavoidable impurities, and where both or any of {110} <223> and {110} <111> in a layer corresponding to 1/8 of the thickness of The sheet has a pole density of 10 or more and a Young's modulus in the rolling direction greater than 230 GPa: and another embodiment of a Young's high modulus steel sheet, where it has a chemical composition, in% in mass, from C: 0.0005 to 0.30%, If: 2.5% or less, Mn: 0.1 to 5.0%, P: 0.15% or less, S: 0.015% or less, At: 0.15% or less, N: 0.01% or less, and further comprises 0.015 to 1.91% by mass in total of one or more Mo: 0.005 to 1.5%, Nb: 0.005 to 0 , 20%, Ti: (48/14 XN)% to 0.2% and B: 0.0001 to 0.01%, and the rest: Inevitable faith and impurities, and where {110} <223> and / or {110} <111> in a layer corresponding to 1/8 of the thickness of the sheet have a pole density of 10 or more and a Young's modulus in the rolling direction greater than 230 GPa.
JP 1015319 A describes a high tensile steel plate that has an excellent resistance characteristic to the generation of fragility fractures of a welded zone affected by heat. Steel consisting of% by weight of 0.03 ~ 0.15% C, 0.05 ~ 0.5% Si, 0.5 ~ 2% Mn, <0.003% N, 3x [N] ~ 0.02 % Ti and 0.005 ~ 0.05% Al is heated to 900-1050 ° C. Once the steel has been heated, the steel is subjected to the pass to reach a
rolling form ratio> 1a expressed by the equation ® ~ 2-jR (Ho W) (Ho H) ^ where | _ | 0- e | thickness before the pass, H: the thickness after the pass, R: the diameter of the rolling mill roll) in the austenite region without crystallization of the transformation point Ar3 (transformation point Ar3 + 100 ° C) . The steel plate is cooled at a cooling rate of 500-600 ° C to> 2 ° C / s immediately after the completion of this hot rolling.
Description of the invention
The present invention provides a steel sheet having a high Young's modulus with a high Young's modulus in the rolling direction, where the longitudinal Young's modulus measured by the static tension method becomes 220 GPa or more when it is use a building material or a car member or other longitudinal member and a method of production thereof.
In this sense, the crystalline orientation is usually shown by the expression {hkl} <uvw> where {hkl} indicates the orientation of the sheet surface and <uvw> indicates the orientation in the rolling direction. Therefore, to obtain a high Young's modulus in the rolling direction, it is necessary to control the operation so that the orientation in the rolling direction <uvw> is adapted to the orientation of the Young's high modulus to the greatest extent possible .
Based on this principle, the inventors engaged in studies to obtain a steel sheet having a high Young's modulus with a Young's modulus in a rolling direction measured by the static tension method of 220 GPa or more.
As a result, the inventors recently found that, in order to improve the static Young's modulus in the rolling direction, it is important to add Nb, include Ti and N in predetermined amounts, and suppress recrystallization in the austenitic phase (then called the " phase y ”) and, in addition, if B is added together, the effect becomes noticeable and, in addition, in hot rolling, the rolling temperature and the shape ratio found in the thickness of the sheet on the side of inlet and on the outlet side of the rolling rollers and the diameter of the rolling rollers are important and by controlling them at suitable intervals, the thickness of the layer given by shear deformation on the surface of the sheet of steel
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increases and the texture formed close to the location of a distance from the surface in the direction of the thickness of the sheet corresponding to 1/6 of the thickness of the sheet (called "the part corresponding to 1/6 of the thickness of the sheet") It is also optimized.
In addition, there is no correlation between the energy of lack of stacking that affects the deformation behavior of the phase and that is hot worked and the texture after the transformation. This affects the texture close to the part corresponding to 1/6 of the thickness of the sheet of the surface layer and the central part of the direction of the thickness of the sheet (called "the part corresponding to 1/2 of the sheet thickness" ). Therefore, to obtain a texture with an orientation where Young's modulus is improved in the rolling direction both in the surface layer and in the central part of the sheet thickness, the inventors achieved the discovery that the optimization of The ratio of Mn, Mo, W, Ni, Cu and Cr has an effect on the energy of non-stacking phase and.
The present invention was made based on this finding and has as its essential point the following:
(1) A sheet of steel with a high Young's modulus that has a longitudinal Young's modulus measured by the static tension method of 220 GPa or more, consisting of mass percentages, in C: 0.005 to 0.200%, Si : 2.50% or less, Mn: 0.10 to 3.00%, P: 0.150% or less, S: 0.0150% or less, Al: 0.010 to 0.155%, N: 0.0005 to 0, 0100%, Nb: 0.005 to 0.100%, and Ti: 0.002 to 0.150%, optionally one or more of Mo: 0.01 to 1.00%, Cr: 0.01 to 3.00%, W: 0.01 at 3.00%, Cu: 0.01 to 3.00% and Ni: 0.01 to 3.00%, B: 0.0005 to 0.0100%, Ca: 0.0005 to 0.1000%, Rem: 0.0005 to 0.1000% and V: 0.001 to 0.100%, consisting of mass% of C: 0.005 to 0.200%, If: 2.50% or less, Mn: 0.10 to 3.00 %, P: 0,150% or less, S: 0,0150% or less, Al: 0,010 to 0,150%, N: 0.0005 to 0,0100%, Nb: 0,005 to 0,100% and Ti: 0,002 to 0,150%, optionally contains one or more Mo: 0.01 to 1.00%, Cr: 0.01 to 3.00%, W: 0.01 to 3.00%, Cu: 0.01 to 3.00% and Ni: 0.01 to 3.00%, B: 0.0005 to 0.0100%, Ca: 0.0005 to 0.1000%, Rem: 0.0005 to 0.1000% and V: 0.001 to 0.100%, which satisfies formula 1, in which the rest is Fe and inevitable impurities, which has a sum of the ratio of random intensity of X-rays in the orientation {100} <001 > and the ratio of random intensity of X-rays in the orientation of {110} <001> of 5 or less in a one-way position from the surface of the steel sheet in the direction of the sheet thickness of 1/6 of the thickness of the sheet, and having a sum of the maximum value of the ratios of random intensity of X-rays of the orientation group {110} <111> to {110} <112> and the ratio of random intensity of X-rays of the orientation {211} <111> of 5 or more:
Ti-48/14 * N> 0.0005 ... formula 1
where, Ti and N are the contents (mass%) of the elements
(2) A sheet of steel with Young's high modulus as set out in (1), characterized by complying with the following formula 2:
4 <3.2Mn + 9.6Mo + 4.7W + 6.2Ni + 18.6Cu + 0.7Cr <10 ... formula 2
where, Mn, Mo, W, Ni, Cu and Cr are the contents (mass%) of the elements
(3) A sheet of steel with Young's high modulus as established in any one of the above (1) or (2), characterized by having a ratio of random intensity of X-rays in the orientation of {332} <113> (A) of 15 or less and a ratio of random intensity of X-rays in the orientation of {225} <110> (B) of 5 or more in a central part of the steel sheet in the direction of the thickness of the sheet and for complying with (A) / (B) <1.00.
(4) A sheet of steel with Young's high modulus as set forth in any one of the above (1) to (3), characterized by having a ratio of random intensity of X-rays in the orientation of {332} <113> (A) of 15 or less and a simple average of the ratio of random intensity of X-rays in the orientation of {001} <110> and a ratio of random intensity of X-rays in the orientation of {112} <110> ( C) of 5 or more in a central part of the steel sheet in the direction of the thickness of the sheet and to be fulfilled (A) / (C) <1.10.
(5) A sheet of steel with a high Young's modulus as set forth in any one of the above (1) to (4), characterized by having a Young's modulus in the rolling direction measured by the static tension method of 220 GPa or more.
(6) A hot dipped galvanized steel sheet, characterized in that it comprises a high modulus Young's steel sheet as set forth in any one of the above (1) to (5), which is hot dipped galvanized .
(7) A hot-dip galvanized and annealed steel sheet, characterized in that it comprises a steel sheet with a high Young modulus as set forth in any one of the above (1) to (5) that is galvanized and annealed by hot dipping
(8) A method of producing a Young high modulus steel sheet that has a Young modulus
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longitudinal measured by the static tension method of 220 GPa or more, characterized by rolling a steel slab that has the chemical ingredients listed above in (1) or (2) at 1,100 ° C or less for a rolling rate up to final pass of 40% or more and for an X-shape ratio found by the following formula 3 of 2.3 or more by two passes or more, hot rolling at a final pass temperature of the transformation point Ar3 at 900 ° C , and winding at 700 ° C or less:
Form ratio X = ld / hm ... formula 3
where, ld (contact arc length between the rolling rollers and the steel sheet): V (Lx (inlet-
output) / 2)
hm: (input + output) / 2
L: diameter of the rolling rollers
Inlet: sheet thickness of the inlet side of the rolling roller Exit: sheet thickness of the inlet side of the rolling roller
(9) A method of producing a sheet of steel with Young's high modulus as set out in (8), characterized by hot rolling so that the effective £ * deformation calculated by the following formula 5 becomes 0, 4 or more:
image 1
where, n is a number of laminator boxes of a final hot rolling mill, £ j is a deformation given in the box, £ n is a deformation given in one nth box, ti is a travel time between ai ai + 1st boxes, and Ti is calculated by the following formula 6 by means of a constant of the gases R (= 1,987) and a rolling temperature Ti (K) of a box:
image2
(10) A method of producing a steel sheet with Young's high modulus as set out in (8) or (9) characterized by carrying out a differential peripheral speed rate of at least one hot rolling pass of 1 % or more.
(11) A method of producing a Young high modulus steel sheet, characterized by hot dip galvanizing a surface of a steel sheet produced by the method as set forth in any of the above (8) to ( 10).
(12) A method of producing a hot-dip galvanized and annealed steel sheet, characterized by hot-dip galvanizing of a surface of a steel sheet produced by a method as set forth in any of the above (8) to (10), then heat it in a temperature range of 450 to 600 ° C for 10 seconds or more.
According to the present invention above, it is possible to obtain a sheet of steel with high Young's modulus improved in the static Young's modulus in the rolling direction measured by the static tension method.
Brief description of the drawings
FIG. 1 is a view showing a relationship of a value of formula 2 of the present invention and a static Young's modulus in the rolling direction.
FIG. 2 is a view showing a crystalline orientation (FDO) distribution function in a cross section of Euler's angle of 92 = 45 ° and a main orientation.
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Best way to carry out the invention
Texture changes in the thickness direction of a steel sheet. When the texture differs from a surface layer and a central part of the direction of the thickness of a sheet, the stiffness, that is, Young's modules, in tensile deformation and flexion deformation, do not necessarily have to coincide. This is due to the fact that stiffness in tensile deformation is a characteristic that is affected by the texture of the entire thickness of a steel sheet and the stiffness in flexural deformation is a characteristic that is affected by the texture of the surface layer of a part of the steel sheet.
The present invention is a steel sheet that optimizes the texture towards a location of a surface distance in the direction of the thickness of the sheet corresponding to 1/6 of the thickness of the sheet and increases Young's modulus in the rolling direction.
Therefore, the texture that contributes to Young's modulus in the rolling direction is formed at least to a position deeper than the part corresponding to 1/8 of the thickness of the sheet, that is, the part corresponding to 1/6 of the thickness of the sheet. By increasing the thickness of the Young's modulus region increased in the rolling direction, it is possible to increase Young's modulus not only for bending deformation, but also for tensile deformation and compression deformation.
In addition, to introduce a shear deformation not only to the surface layer, but also to the part corresponding to 1/6 of the thickness of the sheet, the sheet is produced by the elevation of the ratio determined by the thickness of the sheet before and after a hot rolling pass and the diameter of the rolling rollers.
The steel sheet of the present invention concentrates the orientations that raise the Young's modulus in the rolling direction of at least the surface layer corresponding to the part corresponding to 1/6 of the thickness of the sheet and suppresses the concentration of the orientations that reduce Young's modulus. The static Young's modulus in the rolling direction is high and the stiffness in tensile deformation is high, not only in the surface layer, but also in the part corresponding to 1/6 of the sheet thickness. In addition, by concentrating the orientations that raise Young's modulus in the rolling direction at the location of the surface layer corresponding to the part corresponding to 1/6 of the sheet thickness, the concentration of the orientations that reduce the modulus de Young is also suppressed.
The steel sheet of the present invention specifically has a sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and the ratio of random intensity of X-rays in the orientation of {110} <001> of the part corresponding to 1/6 of the thickness of the sheet of 5 or less and has a sum of the maximum value of the ratios of random intensity of X-rays in the orientation group of {110} <111> to {110} <112 > and the ratio of random intensity of X-rays in the orientation of {112} <111> of 5 or more. The steel sheet of the present invention is obtained by the action of the shear force of the surface layer of the steel sheet with at least the part corresponding to 1/6 of the thickness of the sheet in hot rolling.
In order to make the shear force of the hot rolling act in the part corresponding to 1/6 of the thickness of the sheet of the steel sheet, the inventors discovered that the X-shape relationship defined by the following formula must be 2 , 3 or more in at least two passes between the total number of hot rolling passes.
The X-shape ratio, as shown by the following formula 3, is the ratio of the length of the contact arc of the rollers, the steel and the average thickness of the sheet. The inventors recently discovered that the higher the value of this X-shape relationship, the deeper the part of the steel sheet in the thickness direction of the sheet in which the shear force acts.
Form ratio X = ld / hm ... formula 3
where, ld (length of the contact arc of the rolling rollers and the steel sheet): V (Lx (slit-out) / 2)
hm: (input + output) / 2
L: diameter of the rolling rollers
Inlet: sheet thickness on the inlet side of the rolling roller Exit: sheet thickness on the outlet side of the rolling roller
With a single pass where the X-shape ratio discovered by the following formula 3 is 2.3 or more, shear deformation cannot be introduced in the part corresponding to 1/6 of the sheet thickness. For this reason, the thickness of the layer into which shear deformation was introduced (called "shear layer") is insufficient. The texture near the part corresponding to 1/6 of the thickness of the sheet also deteriorates and Young's modulus measured by the static tension method decreases. Therefore, the number of passes, where the ratio of form X is 2.3 or more, has to be two passes or more.
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The higher the number of passes, the better. The X-shape relationship of all passes can also be 2.3 or more. To increase the thickness of the shear layer, the higher the value of the X-shape ratio, the better. It is preferably 2.5 or more, more preferably 3.0 or more.
In addition, in case of laminating the sheet in an X-shape ratio of 2.3 or more at a high temperature, sometimes subsequent recrystallization causes the texture that elevates Young's modulus to be destroyed. For this reason, lamination that limits the number of passes where the X-shape ratio is 2.3 or more has to be performed at 1,100 ° C or less.
Note that when laminating the sheet at 1,100 ° C or less, the formation in the orientation of <001> {100} and in the orientation of {110} <001> that reduce Young's modulus in the rolling direction is notable due to the introduction of shear deformation at a higher temperature. For this reason, to suppress the concentration of these orientations, it is preferable to suppress the shape ratio of the lamination at a high temperature. On the other hand, the formation in the orientation group of {110} <111> to {110} <112> and in the orientation of {211} <111> that raise Young's modulus in the rolling direction is made notable by the introduction of shear deformation at a low temperature. Therefore, the lower the lamination temperature, the more noticeable the effect of the shape ratio will be, whereby rolling with an X-shape ratio of 2.3 or more is preferably performed by a laminator box near the final.
In addition, to optimize the texture of the total thickness of the surface with the center of the thickness of the sheet, it is preferable to limit the ingredients to make the non-stacking energy of the austenitic phase be produced by heating the hot rolling (called the "phase and") in the optimum range and lamination is carried out in conditions where shear deformation becomes deeper. Because of this, it is possible to suppress the orientations that reduce Young's modulus of the formation in the central part of the thickness of the sheet and raise the static Young's modulus of the thickness of the sheet as a whole.
The fact that the difference in stacking energy has a great effect on the work texture of the phase and that it has a cubic structure centered on the faces has been known before. In addition, when the phase is worked and during hot rolling, it is then cooled and transformed into the ferrite phase (called the “phase a”), the phase a is transformed into an orientation that has a certain relationship of orientation with the crystalline orientation of the phase and before the transformation. This is the phenomenon called "variant selection".
The inventors discovered that the change in texture due to the deformation introduced by hot rolling is affected by the energy of non-stacking of the phase and. That is to say, the texture changes are due to the energy of lack of stacking of the phase and between the surface layer in which the shear deformation is introduced and the central layer in which the compression deformation is introduced.
For example, in case the energy of lack of stacking becomes greater, in the surface layer of the steel sheet part, the orientation concentration that further elevates Young's modulus in the rolling direction, that is, in the orientation of {110} <111>, it becomes greater and, in the central part of the thickness of the sheet, the orientation of {332} <113> that reduces Young's modulus in the direction is developed of lamination. On the other hand, in the event that the lack of stacking energy falls, the orientation concentration of {110} <111> will not raise the surface layer corresponding to the part corresponding to 1/6 of the sheet thickness. In particular, near the part corresponding to 1/6 of the thickness of the sheet, the orientations that reduce Young's modulus, that is, {100} <001> and <110> <001>, develop easily. In contrast to this, in the event that the lack of stacking energy falls, in the central part of the thickness of the sheet, relatively advantageous orientations are formed with respect to the Young's modulus in the rolling direction, that is, the orientation of {225} <110> and the orientation of {112} <110>.
Therefore, in order to raise the static Young's modulus in both the surface layer and in the central part of the thickness of the sheet, it is necessary to control the energy of non-stacking of the phase and at a suitable interval. Specifically, preferably the following formula 2 is met:
4 <3.2Mn + 9.6Mo + 4.7W + 6.2Ni + 18.6Cu + 0.7Cr <10 ... formula 2
where Mn, Mo, W, Ni, Cu and Cr are the contents (mass%) of the elements.
The above formula 2 is based on the formula for the conversion of the effects of the elements on the non-stacking energy of austenite-based stainless steel that has a phase and with respect to the numerical values and is modified by additional tests and studies made by the inventors. Specifically, the inventors investigated the static Young's modulus in the rolling direction in case of converting 0.03% of C, 0.1% of Si, 0.5% of Mn, 0.01% of P, 0.0012 % S, 0.036% Al, 0.010% Nb, 0.015% Ti, 0.0012% B, 0.0015% N in the composition of the basic ingredients and change the amounts of addition of Mn, Cr, W, Cu, and Ni in various ways.
Hot rolling is performed at a final pass temperature of the transformation point Ar3 at 900 ° C, a rolling rate of 1,100 ° C with a final pass of 40% or more, and a shape ratio of 2.3 or more for two passes or more. Note that the transformation temperature Ar3 is calculated by the following formula 4:
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Ar3 = 901-325xC + 33xSi + 287xP + 40xAl-92x (Mn + Mo + Cu) - 46x (Cr + Ni) ... formula 4
where C, Si, P, Al, Mn, Mo, Cu, Cr, and Ni are the contents of the elements (mass%), a content of an extension of an impurity that is indicated as "0". In addition, to simulate winding at 700 ° C or less after lamination, the sheet is heat treated by keeping it at 650 ° C for 2 hours.
Because of the steel sheet, a test piece was extracted according to Japanese Industrial Standard JIS Z 2201 No. 13 using the rolling direction as the longitudinal orientation. A tensile stress equivalent to 1/2 of the yield strength of the steel sheet was provided and the static Young's modulus was measured. The measurement was made five times. The average value of the three measurement values minus the upper value and the lower value between Young's modules calculated based on the inclination of the stress-strain graph was performed with Young's module by the static tension method.
The results are shown in FIG. 1. From this, it is found that when the value of this ratio discovered by the inventors is from 4 to 10, a high static Young's modulus is obtained in the rolling direction greater than 220 GPa, while in case it is lower to 4 or greater than 10, the value decreases markedly.
Hereinafter, the ratio of random intensity of X-rays and Young's modulus of the steel sheet of the present invention will be explained.
Sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and ratio of random intensity of X-rays in the orientation of {110} <001> in the part corresponding to 1/6 of the thickness of the sheet:
The orientation of {100} <001> and the orientation of {110} <001> are orientations that significantly reduce Young's modulus in the rolling direction. When the vibration method is used to measure Young's modulus of the steel sheet, the effect of the texture of the surface layer is the greatest. The effect of the texture is small inside the thickness direction of the sheet. However, when the static tension method is used to measure Young's modulus of the steel sheet, the texture of not only the surface layer, but also the texture of the inside of the thickness direction of the sheet have an effect.
To raise the Young's modulus measured by the tension method, it is necessary to raise the Young's modulus of at least the surface layer corresponding to the part corresponding to 1/6 of the sheet thickness. Therefore, to raise Young's modulus in the rolling direction measured by the tension method, the sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and the ratio of random intensity of X-rays in the orientation of {110} <001> of the part corresponding to 1/6 of the thickness of the sheet must be 5 or less. From this point of view, 3 or less is more preferable.
Note that the orientation of {100} <001> and the orientation of {110} <001> are easily formed near the part corresponding to 1/6 of the sheet thickness when produced only in the surface layer of Shear deformation steel sheet. On the other hand, although only shear deformation is introduced near the part corresponding to 1/6 of the thickness of the sheet, the formation of the orientation of {100} <001> and the orientation of {110} <001> in this location is deleted and the targeting group of {110} <111> to {110} <112> and the targeting of {211} <111> are explained below.
Sum of the maximum value of random X-ray intensity ratios in the orientation group of {110} <111> to {110} <112> and the random X-ray intensity ratio in the orientation of {211} <111> in the part corresponding to 1/6 of the thickness of the sheet:
These are effective crystalline orientations for raising Young's modulus in the rolling direction and are formed due to the shear deformation introduced at the time of hot rolling. The sum of the maximum value of the ratios of random intensity of X-rays in the orientation group of {110} <111> to {110} <112> and the ratio of random intensity of X-rays in the orientation of {211} <111 > in the part corresponding to 1/6 of the thickness of the sheet is 5 or more means that a texture that elevates Young's modulus in the rolling direction has been formed from the surface of the steel sheet in the part corresponding to 1/6 of the thickness of the sheet. Because of this, the static Young's modulus in the rolling direction measured by the tension method becomes 220 GPa or more. Preferably, 10 or more, more preferably 12 or more.
The ratios of random intensity of X-rays in the orientation of {100} <001>, in the orientation of {110} <001>, and in the orientation group of {110} <111> to {110} <112> and in the orientation of {211} <111> they can be found from the crystalline orientation distribution (FDO) function that shows the three-dimensional texture calculated by the serial expansion method based on a plurality of pole poles between the poles of poles {110}, {100}, {211} and {310} measured by X-ray diffraction.
Note that the “ratio of random intensity of X-rays” is the value obtained by measuring
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X-ray intensities of a standard sample that does not have a concentration in a specific orientation and a test sample under the same conditions by the X-ray diffraction method etc. and the division of the x-ray intensity obtained from the test sample by the x-ray intensity of the standard sample.
FIG. 2 shows the FDO of cross section 92 = 45 ° by which the crystalline orientations of the present invention are expressed. FIG. 2 is a Bunge expression that shows the three-dimensional texture by a crystalline orientation distribution function. The angle of Euler 92 is represented at an angle of 45 ° and the specific crystalline orientation (hkl) [uvw] is shown by the angles of Euler 91, O of the crystalline orientation distribution function. As shown by the points on the 0 = 90 ° axis of FIG. 2, the orientation group of {110} <111> to {110} <112> indicates, strictly speaking, the range of 0 = 90 ° and 91 = 35.26 to 54.74 °. However, sometimes a measurement error occurs due to the work of the test sample or the adjustment of the sample, so that the maximum value of the X-ray random intensity relationships in the orientation group of {l10} < l1l> a {110} <112> is performed in the ratio of maximum random X-ray intensity in the range of 0 = 85 to 90 ° and 91 = 35 to 55 ° shown by the shading in the figure.
Due to similar reasons, in the cross section 92 = 45 ° of the three-dimensional texture, on the positions shown by the points of FIG. 2, the maximum values in the orientation of <111> {211} in the range of 91 = 85 to 90 ° and 0 = 30 to 40 °, the orientation of {100} <001> in the range of 91 = 40 to 50 ° and 0 = 0 to 5 °, and the orientation of {110} <001> in the range of 91 = 85 to 90 ° and 0 = 85 to 90 ° are performed in the intensity ratios of these orientations.
In this case, for the crystalline orientation, normally the vertical orientation with respect to the surface of the sheet is expressed as [hkl] or {hkl} and the orientation parallel to the rolling direction is expressed by (uvw) or <uvw>. {hkl} and <uvw> are general terms for equivalent surfaces, while [hkl] and (uvw) indicate individual crystalline surfaces. That is, in the present invention, the body-centered cubic structure (referred to as the "ccc structure") is covered, so, for example, surfaces (111), (-111), (1-11), (11-1), (-1-11), (-11-1), (1-1-1), and (-1-1-1) are equivalent and cannot be distinguished. In this case, these orientations refer to the set "{111}".
Note that the FDO is used to show the orientations of the crystalline structure of low symmetry, so it is generally expressed by 91 = 0 to 360 °, 0 = 0 to 180 °, 92 = 0 to 360 °. Individual orientations are shown by [hkl] (uvw). However, in the present invention, since the structure c.c.c. Highly symmetric is covered, 0 and 92 are expressed in the range of 0 to 90 °. In addition, at the time of the calculation of 91, the interval changes depending on whether symmetry is taken into account due to deformation. In the present invention, symmetry is considered and 91 is expressed as 91 = 0 to 90 °, that is, the average value of the same orientation in the range of 91 = 0 to 360 ° is expressed in FDO 0 to 90 ° . In this case, [hkl] (uvw) and {hkl} <uvw> are synonyms. Therefore, for example, the ratio of random X-ray intensity of (110) [1-11] of the FDO in cross section 92 = 45 ° shown in FIG. 2 is the ratio of random intensity of x-rays in the orientation of {110} <111>.
Samples for X-ray diffraction can be prepared as follows:
The steel sheet is polished and ground by mechanical polishing, chemical polishing, etc. in a predetermined position in the direction of the thickness of the sheet corresponding to a mirror surface, then it is polished by electrolytic polishing or chemical polishing to eliminate deformation and at the same time adjust the sheet so that the part corresponding to 1 / 6 of the thickness of the sheet become the measuring surface.
Keep in mind that making the measuring surface precisely have the part corresponding to 1/6 of the thickness of the sheet is difficult, so it is sufficient to prepare the sample so that the measuring surface is in a range of 3% of the thickness of the sheet from the target position. In addition, in the case where X-ray diffraction measurement is difficult, the EBSP (Electron Back Scattering Pattern) method and the ECP (Electron Channeling Pattern) method ) can be used to measure statistically sufficient values.
If the suppression of the formation of the orientation of {100} <001> and the orientation of {110} <001> to a deeper position in the direction of the thickness of the sheet and the formation of the orientation group of {110} < 111> to {110} <112> and the orientation of {211} <111>, Young's module is further improved. For this reason, by making the texture identical to the surface layer under a deeper position than the part corresponding to 1/6 of the thickness of the sheet, preferably the part corresponding to 1/4 of the thickness of the sheet, more preferably the part corresponding to 1/3 of the thickness of the sheet, the static Young's modulus in the rolling direction is greatly improved.
However, even if shear deformation is introduced from the surface layer to a deeper than normal position as in the present invention, the introduction of shear deformation in the central part of the sheet thickness is impossible. For this reason, it is not possible to form a texture identical to the surface layer in the part corresponding to 1/2 of the thickness of the sheet and a different texture of the surface layer is formed in the central layer of sheet thickness.
Therefore, in addition, to improve the static Young's modulus, it is preferable to improve not only the texture of the layer
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surface with respect to the part corresponding to 1/6 of the thickness of the sheet, but also the texture of the part corresponding to A of the thickness of the sheet with an advantageous orientation to Young's modulus in the rolling direction.
Ratio of random intensity of X-rays in the orientation of {332} <113> (A) and the ratio of random intensity of X-rays in the orientation of {225} <110> (B) in the central part of the thickness of the sheet and (A) / (B):
The orientation of {332} <113> is a representative crystalline orientation that forms in the central part of the sheet thickness and is an orientation that reduces Young's modulus in the rolling direction, while the orientation of {225} <110> is a relatively advantageous orientation for Young's module in the rolling direction.
Therefore, to improve the static Young's modulus in the rolling direction of the central part of the thickness of the sheet, it is preferable that the ratio of random intensity of X-rays in the orientation of {332} <113> (A) in the central part of the thickness of the sheet is 15 or less and the ratio of random intensity of X-rays in the orientation of {225} <110> (B) is 5 or more. In addition, it is preferable that the orientation reduced by Young's modulus in the rolling direction (A) is equal to or less than the orientation raised by Young's modulus in the rolling direction (B), namely, that (A) / (B) is 1.00 or less. From this point of view, (A) / (B) is preferably 0.75 or less, more preferably 0.60 or less. By fulfilling the above condition, it is possible to make the difference between the dynamic Young's module and the static Young's module be within 10 GPa.
Average of the ratios of random intensity of X-rays in the orientation of {001} <110> and in the orientation of {112} <110> in the central part of the thickness of the sheet (C) and (A) / (C ):
In order to make the static Young's modulus in the rolling direction 220 GPa or more, it is preferable to control the laminated texture formed in the central part of the thickness of the sheet and make the Young's modulus in the rolling direction in this part has a value of 215 GPa.
The orientation of {001} <110> and the orientation of {112} <110> are representative orientations where the orientation of <110> coincides with the rolling direction called the "fiber a". This orientation is a relatively advantageous orientation for Young's module in the rolling direction. To improve the static Young's modulus in the rolling direction of the central part of the sheet thickness, it is preferable that the simple average value (C) of the ratios of random intensity of X-rays in the orientation of {001} <110 > and in the orientation of {112} <110> in the central part of the sheet thickness satisfy 5 or more. Furthermore, it is preferable that the orientation that reduces the Young's modulus in the rolling direction (A) is equal to or less than the orientation that the Young's modulus elevates in the rolling direction (C), specifically, that (A) / (C) be 1.10 or less.
The sample for X-ray diffraction in the part corresponding to 1/2 of the thickness of the sheet can also be prepared, in the same way as the sample of the part corresponding to 1/6 of the thickness of the sheet, by polishing to remove the deformation to adjust the sample so that a range within 3% of the part corresponding to 1/2 of the thickness of the sheet becomes the measuring surface. Note that when segregation or other abnormality is recognized in the central part of the sheet thickness, it is preferable to prepare the sample avoiding the segregated part in the range corresponding to 7/16 to 9/16 of the sheet thickness.
However, like the part corresponding to 1/6 of the thickness of the sheet, sometimes a measurement error occurs due to the work of the test piece or the adjustment of the sample. For this reason, in cross section 92 = 45 ° of the three-dimensional texture shown in FIG. 2, the maximum values of the orientation of {001} <110> and the orientation of {225} <110> in the interval 91 = 0 to 5 ° and 0 = 0 to 5 ° and the interval 91 = 0 to 5 ° and 0 = 25 to 35 ° and the orientation of {332} <113> in the range 91 = 85 to 90 ° and 0 = 60 to 70 ° can be used to represent the intensity relationships of these orientations. In addition, the orientation of {112} <110> is in the range 91 = 0 to 5 ° and 0 = 30 to 40 °. For this reason, for example, at 91 = 0 to 5 °, when the maximum value in the range of 0 = 30 to 35 ° becomes greater than 0 = 25 to 30 ° and 0 = 35 to 40 °, the ratio X-ray random intensity of the orientation of {225} <110> and the random X-ray intensity ratio of the orientation of {112} <110> was evaluated as the same numerical value.
Young's modulus is measured by the static tension method by the use of a tensile test piece based on the JIS Z 2201 standard and the transmission of a tensile stress equivalent to A of the yield strength of the steel sheet. That is, Young's modulus is calculated based on not only the tensile stress equivalent to A of the elastic limit, but also based on the inclination of the stress-strain graph obtained. To eliminate variations in measurement, the same test piece is used to be measured five times and the average value of the three measurement methods is performed minus the upper value and the lower value between the results obtained by Young's module.
Next, the reasons for limiting the steel composition in the present invention will be further explained.
Nb is an important element in the present invention. In hot rolling, the
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recrystallization at the time of working the phase and and notably promotes the formation of the texture of work in the phase and. From this point of view, the addition of Nb in an amount of 0.005% or more is necessary. In addition, the addition of 0.010% or more is preferable and the addition of 0.015% or more is preferable. However, if the amount of Nb addition exceeds 0.100%, Young's modulus in the rolling direction decreases, so the upper limit is 0.100%. The reason why the addition of Nb results in a drop in Young's modulus in the rolling direction is not certain, but it is conjectured that Nb has an effect on the energy of non-stacking of phase y. From this point of view, it is preferable that the amount of Nb addition is 0.080% or less, more preferably 0.060% or less.
Ti is also an important element in the present invention. Ti forms nitrides in the high temperature region in phase and suppresses recrystallization at the time of working the phase and in hot rolling. In addition, when B is added, due to the formation of Ti nitrides, the precipitation of BN is suppressed, so that the solid solute B can be ensured. Because of this, the formation of a preferable texture for the improvement of Young's modulus is promoted. To obtain this effect, Ti has to be added in an amount of 0.002% or more. On the other hand, if Ti is added more than 0,150%, the workability deteriorates markedly, so this value serves as an upper limit. From this point of view, it serves as a limit of 0,100% or less. More preferably it serves as a limit 0.060% or less.
N is an impurity. With an amount less than 0.0005%, this results in higher costs, but not a great effect is obtained, so the content is 0.0005% or more. In addition, N forms a nitride with Ti and suppresses the recrystallization of the phase and, so it can be deliberately added, but reduces the effect of suppressing the recrystallization of B, so it is suppressed to 0.0100% or less. . From this point of view, it is preferably 0.0050% or less, more preferably 0.0020% or less.
In addition, Ti and N must comply with the following formula 1:
Ti-48 / 14xN> 0.0005 ... formula 1
Due to this, the recrystallization suppression effect of the phase is exhibited and due to the precipitation of TiN, the formation of BN in the case of B addition can be suppressed, and the preferable texture formation is promoted for the improvement of the Young's module.
C is an element that increases resistance. The addition of 0.005% or more is necessary. In addition, from the point of view of Young's modulus, the lower limit of the amount of C is preferably 0.010% or more. This is because, if the amount of C decreases to less than 0.010%, the Ar3 transformation temperature rises, hot rolling at low temperature is difficult, and Young's modulus decreases. In addition, to suppress the fatigue characteristics of the welding zone, the content is preferably 0.020% or more. On the other hand, if the amount of C exceeds 0.200%, the conformability deteriorates, so the upper limit was 0.200%. In addition, if the amount of C exceeds 0.100%, the weldability sometimes deteriorates, so it is preferable to make the amount of C 0.100% or less. In addition, if the amount of C exceeds 0.060%, Young's modulus in the lamination direction decreases sometimes, so 0.060% or less is more preferable.
If it is a deoxidizing element. The lower limit is not defined, but being less than 0.001% results in higher production costs. In addition, If it is an element that increases resistance by strengthening the solution. This is also effective in obtaining a structure that includes martensite, bainite, or more residual austenite. For this reason, it can be deliberately added according to the directed resistance level, but if the amount of addition is greater than 2.50%, the press formability deteriorates, so that 2.50% is the upper limit. In addition, if the amount of Si is large, the chemical convertibility decreases, so that the amount is preferably 1.20% or less. In addition, when hot dipping galvanization is performed, sometimes problems arise such as decreased plating adhesion, decreased productivity due to delayed alloy reaction, and other problems, and therefore, it is preferable that the amount of Si is 1.00% or less. From the point of view of Young's module, it is more preferable that the amount of Si is 0.60% or less, more preferably 0.30% or less.
Mn is an important element in the present invention. Mn is a temperature reduction element in which the phase and is transformed into the ferrite phase, that is, the transformation point Ar3, when heated to a high temperature at the time of hot rolling. By adding Mn, the phase and becomes stable at a low temperature and the temperature of the final lamination can be decreased. To obtain this effect, it is necessary to add Mn in an amount of 0.10% or more. In addition, Mn, as explained below, correlates with the non-stacking energy of phase y. It affects the formation of the working texture in the phase and and the selection of variants at the time of transformation, causes the formation of the crystalline orientation to elevate the Young's modulus in the direction of lamination after the transformation, and, by on the contrary, it suppresses the formation of orientation that reduces Young's module. From this point of view, it is preferable to add Mn in an amount of 1.00% or more. More preferably, 1.20% or more of Mn is added. The addition of 1.50% or more is most preferable. On the other hand, if the amount of Mn addition exceeds 3.00%, the static Young's modulus in the rolling direction decreases. In addition, the resistance becomes too high and the ductility decreases, so the upper limit of the amount of Mn is 3.00%. In addition, if the amount of Mn exceeds
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2.00%, the adhesion of zinc plating sometimes deteriorates. From the point of view of Young's modulus in the rolling direction, as well as the amount is preferably 2.00% or less.
P is an impurity, but it can be deliberately added when the resistance has to increase. In addition, P has the effect of achieving a finer hot rolled structure and improves its workability. However, if the amount of addition is greater than 0.150%, the fatigue resistance after spot welding deteriorates and the elasticity limit increases and defects in surface properties are caused at the time of pressure. In addition, when continuous hot-dip galvanization is performed, the alloy reaction becomes extremely slow and this decreases productivity. In addition, secondary capacity for work also worsens. Therefore, 0.15 serves as the upper limit.
S is an impurity. If when it is present in more than 0.0150%, it becomes the cause of the formation of hot cracks and causes a deterioration in the ability to work, so this is its upper limit.
Al is a regulator of deoxidation. From the point of view of deoxidation, it is 0.010% or more. On the other hand, Al significantly increases the transformation point, so that, if the addition is more than 0,150%, lamination in the region and low temperature becomes difficult, so that its upper limit is set to 0,150%
To raise static Young modules of both the surface layer of the thickness of the sheet and the central part, it is preferable to comply with the following formula 2:
4 <3.2Mn + 9.6Mo + 4.7W + 6.2Ni + 18.6Cu + 0.7Cr <10 ... formula 2
In this case, Mn, Mo, W, Ni, Cu and Cr are the contents (mass%) of the elements. Note that when the addition amounts of Mo, W, Ni, Cu, and Cr are less than the preferred lower limit values, the ratio of formula 2 is calculated considering these as "0".
If the above formula 2 is met, the orientation that elevates Young's modulus in the rolling direction is concentrated in the shear layer of the surface layer of the steel sheet or near the central part of the thickness of the sheet and the concentration that reduces Young's modulus in the rolling direction is suppressed. Note that if the above formula 2 exceeds 10, the orientation of {332} <113> that reduces Young's modulus in the rolling direction is easily formed and the orientation formation of {225} <110> or the orientation of {001} <110> and the orientation of {112} <110> that raise Young's modulus in the rolling direction tends to be suppressed.
In addition, in case of addition of Mn and, if necessary, one or two of Mo, W, Ni, Cu and Cr so that the value of formula 2 is preferably set to 4.5 or more, more preferably 5, 5 or more, Young's modulus in the rolling direction can be raised. However, if formula 2 is not met and the value of the ratio exceeds 10, the mechanical properties deteriorate, the texture of the central part of the sheet thickness deteriorates, and the static Young's modulus in the direction of Lamination sometimes decreases, so the value of the ratio is preferably set to 10 or less. From this point of view, 8 or less is more preferable.
Mo, Cr, W, Cu and Ni are elements that affect the energy of non-stacking of the phase and when hot rolling. It is preferable to add one or more types at 0.01% or more. Note that if one or more types of Mo, Cr, W, Cu and Ni and Mn are added together, they have an effect on the formation of the work texture, they form the crystalline orientations that raise Young's modulus in the direction of lamination in the surface layer with respect to the part corresponding to 1/6 of the thickness of the sheet, that is, {110} <111> and {211} <111>, and suppress the formation of the orientations that reduce the modulus of Young, that is, {100} <001> and {110} <001>.
In addition, one or more types of Mo, Cr, W, Cu, and Ni are preferably added together with Mn in order to comply with the foregoing (2). This is because, in the central part of the thickness of the sheet, it is possible to suppress the orientation concentration of {332} <113> that reduces Young's modulus in the rolling direction and raise the concentration of the orientation of {225} <110>, the orientation of {001} <110> and the orientation of {112} <110> that raise Young's module in the rolling direction. In particular, Mo and Cu have high coefficients of the above formula 2. Even if they are added in small quantities, they exhibit the effect of raising Young's modulus, so that the addition of one or both of Mo and Cu is more preferable . In addition, Cr is an element that increases the hardenability to contribute to the improvement of resistance and is also effective for the improvement of corrosion resistance. An addition of 0.02% is preferred.
On the other hand, due to the addition of Mo, the resistance is raised and the ability to work is sometimes deteriorated, so that the upper limit of the amount of Mo addition is preferably set at 1.00%. In addition, from a cost point of view, 0.50% or less of Mo is preferably added. In addition, the upper limit of one or more types of Cr, W, Cu and Ni is, from the point of view of capacity for work, 3.00%. Note that the most preferable upper limits of W, Cu and Ni are, respectively, in mass%, of 1.40%, 0.35% and 1.00%.
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B is an element that significantly suppresses recrystallization by the addition of composite material with Nb and improves hardenability in the solid solute state. It is believed to have an effect on the selectivity of variants of the crystalline orientation at the time of transformation from austenite to ferrite. Therefore, it is believed that to promote the formation of the orientations that elevate Young's module, that is, the orientation group from {110} <111> to {110} <112>, and simultaneously suppress the formation of the orientations which reduce Young's module, that is, the orientation of {100} <001> and the orientation of {110} <001>. From this point of view, the addition of 0.0005% or more is preferable. On the other hand, even if B is added in an amount greater than 0.0100%, no effect can be obtained, so the upper limit is set at 0.0100%. In addition, if B is added in an amount greater than 0.005%, workability is sometimes impaired, so that 0.0050% or less is preferable. 0.0030% or less is more preferable.
Ca, Rem, and V have the effect of increasing mechanical strength or improving material quality. One or more types are preferably included according to need.
If the amounts of Ca and Rem are less than 0.0005% and the amount of addition of V is less than 0.001%, sometimes a sufficient effect cannot be obtained. On the other hand, if the addition amounts of Ca and Rem exceed 0.1000% and the addition amount of V is greater than 0.100%, the ductility is sometimes altered. Therefore, Ca, Rem, and V are preferably added respectively in the ranges of 0.0005 to 0.1000%, 0.0005 to 0.1000% and 0.001 to 0.100%.
Next, the reasons for limiting the production conditions will be explained.
Steel is produced and cast by ordinary methods to obtain the steel slab for use for hot rolling. This steel slab can also be obtained by forging or rolling a steel ingot, but from the standpoint of productivity, it is preferable to use continuous casting to produce a steel slab. In addition, it can be produced by a thin slab casting machine.
In addition, usually a steel slab is cast, then cooled and reheated for hot rolling. In this case, the heating temperature of the steel slab at the time of hot rolling is preferably 1,100 ° C or more. This is because, in case the heating temperature of the steel slab is lower than 1,100 ° C, it is difficult to make the hot rolling finishing temperature of the transformation point Ar3 or more. To efficiently and uniformly heat the steel slab, the heating temperature is preferably set at 1,150 ° C or more. No upper limit is defined for the heating temperature, but if the heating is greater than 1,300 ° C, the glass grain size of the steel sheet becomes irregular and workability sometimes deteriorates. In addition, a process such as continuous casting-direct rolling (CC-LC), which casts molten steel, can then be used in hot rollers.
In the production of the steel sheet of the present invention, the conditions in hot rolling at 1,100 ° C or less are important. The form relationship is defined as explained above. Note that the diameters of the rolling rollers are measured at room temperature. There is no need to consider flatness during hot rolling. The thicknesses of the sheet on the input side and the output side of the rolling rollers can be measured at the point of use of radiant rays, etc., or can be found by calculating the rolling load taking into account the deformation resistance, etc. In addition, hot rolling at a temperature above 1,100 ° C is not particularly defined and can be performed properly. That is, the raw rolling of the steel slab is not particularly limited and can be carried out by an ordinary method.
In hot rolling, the rolling rate at 1,100 C or less until the final pass is set at 40% or more. This is because even if the hot rolling is greater than 1,100 ° C, the structure after work is recrystallized and the effect of raising the ratios of random intensity of X-rays in the orientation group of {110} <111> a {110} <112> in the part corresponding to 1/6 of the thickness of the sheet cannot be obtained.
The rolling rate at 1,100 ° C or less until the final pass is the difference in the thickness of the sheet of the steel sheet at 1,100 ° C and the thickness of the sheet of the steel sheet after the final pass divided by the thickness of the sheet of the sheet of steel at 1,100 ° C expressed as a percentage.
This is because, if this rolling rate is less than 40%, in the part corresponding to 1/6 of the thickness of the sheet, the texture that elevates Young's modulus in the rolling direction does not develop sufficiently. Furthermore, by setting this lamination rate at 40% or more, it is preferable to raise the texture that elevates Young's modulus in the direction of lamination in the part corresponding to A of the thickness of the sheet. To raise Young's modulus in the direction of lamination in the part corresponding to 1/6 of the thickness of the sheet and the part corresponding to A of the thickness of the sheet, this rolling rate is preferably set at 50% or more. In particular, in order to raise Young's modulus in the direction of lamination in the part corresponding to A of the thickness of the sheet, it is preferable to increase the lamination rate to a lower temperature.
Note that when the value of formula 2 above is slightly high, in case the rate is increased
of rolling, in the part corresponding to A of the thickness of the sheet, the formation of the orientation of {225} <110> or the orientation of {001} <110> and the orientation of {112} <110> which they raise Young's modulus in the rolling direction, but the orientation of {332} <113> that reduces Young's modulus in the rolling direction also tends to form more easily.
5 No upper limit is particularly provided for the rolling rate, but if a rolling rate at 1,100 ° C or less until the final pass exceeds 95%, not only the load on the rolling mill is raised, but also the Young's modulus that causes the texture, as well as the change that begins to decrease, so that the rate is preferably set at 95% or less. From this point of view, 90% or less is more preferable.
The final pass temperature of the hot rolling is performed at the transformation point Ar3 or more. This is because, if it is laminated less than the transformation point Ar3, in the part corresponding to 1/6 of the thickness of the sheet, the texture {110} <001> is not preferable for the rolling direction and is They form Young's modules in the transverse direction. Furthermore, if the final pass temperature of the hot rolling is greater than 900 ° C, it is difficult to make the preferable texture elevate the shape of the Young's modulus in the rolling direction and the random intensity ratios of X-rays in the orientation group from {110} <111> to {110} <112> in part 15 corresponding to 1/6 of the thickness of the sheet decreases. To raise Young's modulus in the rolling direction, it is preferable to reduce the rolling temperature of the final pass. Conditional on being the transformation point Ar3 or more, the temperature is preferably 850 ° C or less, more preferably 800 ° C or less.
Note that the transformation temperature Ar3 can be calculated by the following formula 4:
20 Ar3 = 901-325xC + 33xSi + 287xP + 40xAl-92x (Mn + Mo + Cu) -
46x (Cr + Ni) ... formula 4
where, C, Si, P, Al, Mn, Mo, Cu, Cr, and Ni are the contents of the elements (mass%), a content of an extension of an impurity that is indicated as "0".
After finishing hot rolling, the steel strip must be rolled to 700 ° C or less. This is due to the fact that if it is rolled at 700 ° C or more, the sheet can be recrystallized on subsequent cooling, the texture can be destroyed and Young's modulus can decrease. From this point of view, the temperature is preferably set at 650 ° C or less. More preferably, it is set at 600 ° C or less. The lower limit of the winding temperature is not particularly limited, but if the strip is wound at room temperature or less, no particular effect occurs. The load of the complex is simply raised, so that the ambient temperature serves as the lower limit.
In order to effectively introduce the shear deformation of the surface layer of the steel sheet to at least the part corresponding to 1/6 of the thickness of the sheet, it is more preferable to establish that the effective resistance * calculated by the following formula 5 reaches be 0.4 or more:
image3
35 where, n is a number of laminator boxes of a final hot rolling, £ j is a deformation given in the box, £ n is a deformation given in a nth box, ti is a travel time between one year + 1st boxes, and Ti is calculated by the following formula 6 by means of a constant of the gases R (= 1,987) and a rolling temperature Ti (K) of a box:
image4
40 The effective £ * resistance is an indicator of the cumulative resistance taking into account the recovery of dislocations at the time of hot rolling. By setting this to 0.4 or more, it is possible to more effectively ensure the resistance introduced into the shear layer. The greater the effective resistance *, the greater the thickness of the shear layer and the greater the formation of the preferable texture for the improvement of Young's modulus, so that 0.5 or more is preferable and 0.6 or More is more preferable.
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When setting the effective £ * resistance at 0.4 or more, to effectively introduce the shear layer resistance, it is preferable to set the coefficient of friction between the rolling rollers and the steel strip at 0.2. The coefficient of friction can be adjusted by controlling the rolling load, rolling speed, type and amount of lubricant.
When hot rolling is performed, it is preferable to perform the lamination with differential peripheral speed with a differential peripheral speed rate of the rolling rollers of 1% or more for one pass or more. In the case of lamination with differential peripheral speed with a difference in the peripheral speeds of the upper and lower lamination rollers, shear deformation is introduced near the surface layer and texture formation is promoted, so that the Young's module is improved compared to a zero lamination with differential peripheral speed. In this case, the differential peripheral speed rate in the present invention shows the difference in peripheral speeds of the upper and lower lamination rollers divided by the peripheral speed of the roller with low peripheral speed expressed as a percentage. Furthermore, the differential peripheral speed lamination of the present invention is not particularly different in the effect of the Young's modulus improvement regardless of the peripheral speeds of the upper and lower rollers.
The differential peripheral velocity rate of the lamination with differential peripheral velocity is preferably as large as possible to improve Young's modulus. Therefore, the differential peripheral velocity rate is preferably from 1% to 5%. In addition, lamination with differential peripheral velocity is preferably performed by a differential peripheral velocity rate of 10% or more, but setting the differential peripheral velocity rate at 50% or more is currently difficult.
In addition, a particular upper limit is not defined for the number of passes with lamination with differential peripheral speed, but from the point of view of the accumulation of shear deformation introduced, a greater number provides a greater effect on the improvement of the modulus of Young, so that all passes of the lamination at 1,100 ° C or less can also be carried out with lamination with differential peripheral speed. Normally, the number of hot rolling lamination passes exceeds approximately eight passes.
The hot-rolled steel strip produced by this method can, according to need, be pickled, then rolled in or in-line quenching for a rolling rate of 10% or less. In addition, according to the application, it can be hot dipped galvanized or hot dipped galvanized. The zinc plating composition is not particularly limited, but in addition to zinc, Fe, Al, Mn, Cr, Mg, Pb, Sn, Ni, etc. They can be added according to need. Note that temper lamination can also be done after galvanization and alloy treatment.
The alloy treatment was performed in the range of 450 to 600 ° C. If it is less than 450 ° C, the alloy does not continue sufficiently, while, if it is higher than 600 ° C, the excessive alloy continues and the plating layer becomes brittle, so the problem of plating separation is induced due to pressing, etc. The alloy treatment time is set to 10 seconds or more. If it is less than 10 seconds, the alloy does not proceed sufficiently. The upper limit of the alloy treatment is not particularly defined, but, in general, if the treatment is carried out for more than 3,000 seconds by a thermal treatment facility established in the continuous line, productivity will be affected or an investment will be necessary. of capital, increasing production costs.
In addition, before carrying out the alloy treatment, according to the configuration of the production facilities, the steel can be annealed below the Ac3 transformation temperature. If a temperature is below this temperature, the texture does not change much, and it is possible to suppress the fall in Young's modulus.
Examples
Example 1
Steels having the compositions shown in Table 1 (remains of Fe and unavoidable impurities) were produced and cast on steel slabs. The steel slabs were heated, approximately hot rolled, then the finishing laminate under the conditions is shown in Table 2 and Table 3 (continuation of Table 2). The finishing lamination slab consists of a total of six passes. The diameter of the roller was 650 to 830 mm. In addition, the thickness of the finishing strip after the finishing pass was set at 1.6 mm to 10 mm. In addition, in Table 2 and Table 3, SRT (° C) is the heating temperature of the steel slab, FT (° C) is the temperature after the rolling finish pass, that is, the outlet side of the finish, and CT (° C) is the winding temperature. The rolling rate is the difference in the thickness of the strip at 1,100 ° C and the thickness of the final strip divided by the thickness of the sheet at 1,100 ° C and is shown as a percentage. The "form relationship" column shows the values of the form relationships in the different passes. The "-" shown in the "form relationship" column means that
5
10
fifteen
twenty
25
30
35
40
Four. Five
fifty
The lamination temperature in the pass has exceeded 1,100 ° C. In addition, the "Pass / faNo" column of the "form relationship" shows "past" when at least two of the past form relations are greater than 2.3 and "failure" when not.
Note that the blank fields in Table 1 mean that the elements are not deliberately added (the same happens in Table 10). In addition, "formula 1" in Table 1 is the value on the left side of the following formula 1 calculated by the content of Ti and N (mass%):
Ti-48/14 * N> 0.0005 ... formula 1
The W and Y steels of Table 1 are comparative examples without added Ti. "1" is shown in the "formula 1" column.
In addition, "formula 2" in Table 1 is the value on the left side of the following formula 2 calculated based on the contents of Mn, Mo, W, Ni, Cu, and Cr (mass%):
4 <3.2Mn + 9.6Mo + 4.7W + 6.2Ni + 18.6Cu + 0.7Cr <10 ... formula 2
When the contents of Mn, Mo, W, Ni, Cu and Cr come from the impurity extensions, for example, when the Mo, W, Ni, Cu and Cr fields in Table 1 are blank, the left side of Formula 2 is calculated with them as "0".
In addition, Ar3 of Tables 1 to 3 is the Ar3 transformation temperature calculated by the following formula 4:
Ar3 = 901-325xC + 33xSi + 287xP + 40xAl-92x (Mn + Mo + Cu) - 46x (Cr + Ni) ... formula 4
In this case, C, Si, P, Al, Mn, Mo, Cu, Cr, and Ni are the contents of the elements (mass%), a content of an extension of an impurity that is indicated as "0".
A tensile test piece based on the JIS Z 2201 standard was obtained from the steel sheet obtained and a tensile test based on the JIS Z 2241 standard was performed to measure tensile strength. Young's modulus was measured both by the static tension method and by the vibration method.
Young's modulus was measured by the static tension method by using a tensile test piece based on the JIS Z 2201 standard and giving a tensile stress equivalent corresponding to A of the yield strength of the steel sheet. The measurement was carried out five times, the average value of the three measurement values minus the upper value and the lower value between Young's modules calculated based on the inclination of the stress-strain graph was found as Young's module by the static tension method, and this was used as the static Young's module.
The vibration method was performed using the horizontal resonance method at ordinary temperature based on the JIS Z 2280 standard. That is, a sample is provided vibration without being fixed in place, the number of oscillator vibrations was gradually changed to measure the number of primary resonance vibrations, the number of vibrations was used to find Young's modulus by calculation, and this was used as a dynamic Young's modulus.
In addition, the relations of random intensity of X-rays in the orientation of {100} <001> and {110} <001> and the orientation group of {110} <111> to {110} <112> and orientation of {211} <111> of the part corresponding to 1/6 of the thickness of the sheet of the steel sheet were measured as indicated. First, the steel sheet was polished and mechanically ground, then electrolytically polished to eliminate deformation and adjusted so that the part corresponding to 1/6 of the sheet thickness becomes the measuring surface. The sample was used for X-ray diffraction. Note that, X-ray diffraction of a standard sample without concentration in a specific orientation was performed under the same conditions. Then, based on poles of poles {110}, {100}, {211}, {310} obtained by X-ray diffraction, an FDO was obtained by the serial expansion method. From this FDO, the relationships of random intensity of X-rays were found in the orientation of {100} <001> and {110} <001> and the orientation group of {110} <111> to {110} < 112>.
The orientation of {332} <113> and the orientation of {225} <110> of the part corresponding to A of the thickness of the sheet of the steel sheet, in the same way as the sample of the part corresponding to 1 / 6 of the sheet thickness, the results of the FDO were found by X-ray diffraction using adjusted samples so that the part corresponding to A of the sheet thickness became the measuring surface.
In addition, among these steel sheets, hot dipped galvanized after the end of hot rolling was indicated as "hot dipping", and those hot dipped galvanized and annealed at 520 ° C for 15 seconds are indicated as "alloy".
5
10
fifteen
twenty
25
30
35
40
Four. Five
fifty
55
The results are shown in Table 4 and Table 5 (continued from Table 4). Note that "DL" in the Young's module column means the rolling direction and "DT" means the direction perpendicular to the rolling direction, that is, the transverse direction.
As is clear from Table 4 and Table 5, when the hot rolled steel contains the chemical ingredients of the present invention under suitable conditions, Young's modulus by the static tension method both in the rolling direction and in the Perpendicular lamination orientation could exceed 220 GPa. In particular, it is known that when the texture conditions of the central layer of the sheet thickness are simultaneously met, Young's modulus by the static tension method is high and the difference from the vibration method is reduced.
Note that, steel N has a formula 2 value outside the preferred range. This is an example where the texture of the part corresponding to A of the thickness of the sheet is somewhat degraded, the difference between the static Young's module and the dynamic Young's module is extended, and the static Young's module in the rolling direction It decreases a little.
On the other hand, production numbers 43 to 48 are comparative examples of steels U to Z with chemical ingredients outside the range of the present invention.
Production No. 43 is an example of using steel U that contains excessively Nb. The sum of the ratios of random intensity of X-rays in the orientation of {100} <001> and in the orientation of {110} <001> of the part corresponding to 1/6 of the thickness of the sheet is enlarged, the sum of the maximum value of the ratios of random intensity of X-rays in the orientation group of {110} <111> to {110} <112> and the ratio of random intensity of X-rays in the orientation of {2l1} <111> decreases , and, in addition, the ratio of the random intensity of X-rays in the orientation of {332} <113> (A) and the ratio of random intensity of X-rays in the orientation of {225} <110> (B), (A) / (B), of the part corresponding to A of the thickness of the sheet becomes a little lower, and Young's modulus in the rolling direction decreases. The reason why the sum of the random X-ray intensity ratios in the orientations of {100} <001> and {110} <001> is not clear is clear, but it is believed that the excessive addition of Nb caused the formation of a shear texture in the phase and and a change in the selectivity of variants at the time of the subsequent transformation of the phase and to the ferrite phase. Young's modulus in the transverse direction, as it has become known, is obtained as a high value due to the laminated and uncrystallized transformed texture developed from the central layer of the sheet thickness. In the present invention, a similar mechanism also achieves Young's high modulus in the transverse direction.
Production No. 44 is an example of V steel with a small amount of Mn. Young's modulus of rolling direction decreases. This is because, together with the drop in Mn, the transformation temperature Ar3 rises and, as a result, the hot rolling is carried out under the transformation temperature Ar3 and the orientation concentration of {110} < 001> rises.
Production No. 45 is an example of steel W that does not contain Ti and does not comply with formula 1. In addition, the calculated value of formula 2 is also less than a preferable lower limit value, the sum of the ratios X-ray random intensity in the orientation group of {110} <111> to {110} <112> and the ratio of random X-ray intensity in the orientation of {211} <111> of the part corresponding to 1 / 6 of the thickness of the sheet decreases, and Young's modulus in the rolling direction decreases.
Production numbers 46 to 48 are examples that use X steel that do not comply with formula 1, Y steel that does not contain Ti and that does not comply with formula 1, and Z steel does not contain Nb. The sum of the ratios of random intensity of X-rays in the orientation group of {110} <111> to {110} <112> and the ratio of random intensity of X-rays in the orientation of {211} <111> decreases and Young's modulus in the rolling direction decreases. In Z steel, Young's modulus in the transverse direction also decreases simultaneously, but this is because almost no element for suppression of recrystallization is added to Z steel, so it was assumed that the formation of the Transformed texture laminated in the central part of the sheet thickness was insufficient.
In addition, as shown by the comparative examples of steels C and J, that is, production numbers 8 and 24, if there are few passes where the shape ratio is 2.3 or more, even if You get a high Young's modulus with the vibration method, you can't get more than 220 GPa by the static tension method.
The comparative example of steel B, that is, production No. 5, and the comparative example of steel G, that is, production No. 18, have high finishing temperatures FT (° C) of rolling in hot, they have a sum of falling X-ray random intensity ratios in the orientation group of {110} <111> to {110} <112> and the orientation of {211} <111> preferable for module improvement of Young in the direction of lamination in the part corresponding to 1/6 of the thickness of the sheet, and do not form any texture in all directions of the thickness of the sheet, whereby the Young's modulus in the transverse direction also decreases.
The comparative example of steel K, that is, production number 27, is an example where the winding temperature CT (° C) is high and the sum of the ratios of random intensity of X-rays in the orientation group of {110} <111> to {110} <112> and the orientation of {211} <111> preferable for the improvement of Young's module in the
rolling direction in the part corresponding to 1/6 of the thickness of the sheet decreases.
The comparative example of steel E, that is, production no. 13, has a reduced heating temperature SRT (° C) of the steel slab, is an example where the finishing temperature FT (° C) of the Hot rolling decreases below the Ar3 transformation temperature and, for this reason, in part 5 corresponding to 1/6 of the sheet thickness, the ratio of random intensity of X-rays in the orientation of {100} <001 > becomes larger and Young's modules in the rolling direction and in the transverse direction decrease.
The comparative example of steel H, that is, production number 20, is an example where the lamination rate of the finishing lamination, that is, the lamination rate at 1,100 ° C or less, is low, for so the sum of the 10 ratios of random intensity of X-rays in the orientation group of {110} <111> to {110} <112> and the orientation of {211} <111> decreases and Young's modules in the rolling direction and in the transverse direction decrease.
The comparative example of steel N, that is, production number 35, is an example where the rolling rate at 1,100 ° C or less of the hot rolling is low and the number of passes where the shape ratio is 2.3 or 15 more is small, so the ratios of random intensity of X-rays in the orientation group from {110} <111> to {110} <112> decrease and Young's modules in the rolling direction and in the transverse direction decrease.
 Steel  Ingredients (% by mass) Form 1 Form 2 Ar3 ° C Remarks
 C  If Mn P S Al N Nb Ti B Cr, W, Cu, Ni Mo Ca, V, Rem
 TO  0.007 0.01 1.30 0.012 0.0040 0.030 0.0018 0.025 0.020 0.0008 Cr: 0.02, Cu: 0.03 0.014 4.73 780 Ex. Of the invention
 B  0.020 0.01 2.10 0.008 0.0060 0.050 0.0021 0.040 0.025 0.0013 0.018 6.72 706
 C  0.050 0.60 1.60 0.008 0.0050 0.060 0.0019 0.035 0.030 0.0017 Cr: 0.03 0.15 0.023 6.54 747
 D  0.050 0.01 1.20 0.009 0.0050 0.035 0.0030 0.012 0.020 0.0015 Cr: 0.04, Cu: 0.05 0.010 4.80 772
 AND  0.060 1.50 0.50 0.006 0.0060 0.040 0.0025 0.015 0.018 Cr: 0.04, Cu: 0.15, Ni: 0.08 0.009 4.91 869
 F  0.080 0.01 1.60 0.010 0.0050 0.045 0.0021 0.030 0.020 0.0018 Cr: 0.03, Cu: 0.02 0.013 5.51 730
 G  0.050 0.90 1.50 0.008 0.0060 0.032 0.0023 0.036 0.030 0.0021 0.10 0.022 5.73 771
 H  0.035 0.01 1.60 0.012 0.0010 0.035 0.0018 0.042 0.034 0.0023 Ca: 0.0005 0.028 5.12 748
 I  0.070 0.30 1.80 0.011 0.0040 0.041 0.0017 0.020 0.029 0.0009 W: 0.30 0.023 7.17 727
 J  0.040 0.01 1.70 0.009 0.0040 0.036 0.0020 0.030 0.018 0.0024 0.20 0.011 7.30 718
 K  0.060 0.50 1.30 0.008 0.0060 0.033 0.0023 0.019 0.023 0.0032 Cr: 0.02, Cu: 0.04 0.015 4.92 777
 L  0.080 0.80 1.60 0.006 0.0090 0.045 0.0024 0.021 0.045 0.0019 Cr: 0.50, Cu: 0.06 0.037 6.59 729
 M  0.050 0.01 0.90 0.013 0.0030 0.042 0.0022 0.036 0.018 0.0036 Cu: 0.28, Ni: 0.14 0.010 8.96 775
 N  0.030 0.30 1.80 0.040 0.0050 0.039 0.0026 0.038 0.025 0.0025 Cu: 0.20, Ni: 0.10 0.20 Rem: 0.002 0.016 11.96 707
 0  0.050 1.20 1.65 0.021 0.0070 0.040 0.0040 0.042 0.036 0.0018 Cu: 0.13, Ni: 0.07 0.022 8.13 765
 P  0,120 0.60 1.80 0.010 0.0040 0.034 0.0036 0.028 0.035 0.0009 V: 0.020 0.023 5.76 720
 Q  0,150 1.20 1.40 0.013 0.0030 0.060 0.0028 0.035 0.040 0.0012 Cr: 0.50, W: 0.18 0.08 0.030 6.42 739
 R  0.040 1.60 2.10 0.015 0.0040 0.035 0.0019 0.029 0.027 0.0016 0.35 0.020 9.98 721
 S  0.100 0.01 1.40 0.012 0.0040 0.036 0.0026 0.031 0.038 Cu: 0.20, Ni: 0.10 0.029 8.20 727
 T  0.040 0.01 1.60 0.009 0.0003 0.022 0.0026 0.015 0.080 0.071 5.12 745
 OR  0.028 0.01 1.50 0.009 0.0060 0.045 0.0020 0.180 0.031 0.0015 0.024 4.80 759 Comparative example
 V  0.040 1.60 0.08 0.012 0.0050 0.040 0.0020 0.030 0.015 0.0020 Cr: 0.02, Cu: 0.01, Ni: 0.03 0.008 0.64 935
 w  0.060 0.01 1.00 0.030 0.0050 0.032 0.0023 0.035 - 3.20 800
 X  0.050 0.05 2.30 0.008 0.0070 0.035 0.0035 0.035 0.008 0.0036 W: 0.20 -0.004 8.30 678
 Y  0.060 0.30 1.30 0.006 0.0020 0.036 0.0039 0.0029 Cr: 0.50, Cu: 0.06, Ni: 0.02 - 5.75 746
 z  0.080 0.60 1.50 0.009 0.0030 0.029 0.0025 0.025 Cr: 0.02, Cu: 0.03 V: 0.005 0.016 5.37 757


 Product No.  Steel Ar3 SRT Form Ratio FT CT Coating Remarks
 ° C ° C  Lamination% 1P 2P 3P 4P 5P 6P Pass / Fail  ° C ° C
 one      1250 65 - 3.92 4.69 5.69 6.36 5.31 Pass 885 500 Hot dip Ex. Of inv.
 2  A 780 1150 79 2.56 3.47 5.00 5.69 5.73 4.85 Pass 850 550 Ex. Of inv.
 3      1200 55 2.64 3.50 5.29 5.83 6.20 4.94 Pass 863 550 Ex. Of inv.
 4  B 706 1250 77 - 3.02 4.21 4.45 4.76 3.59 Pass 876 600 Ex. Of inv.
 5  1230 79 2.68 3.64 5.34 6.09 6.00 4.65 Pass 920 550 Comp.
 6      1200 76 2.32 2.93 4.19 4.12 4.19 3.51 Pass 818 450 Ex. Of inv.
 7  C 747 1250 80 - 3.57 5.23 5.92 6.11 5.23 Pass 885 500 Ex. Of inv.
 8      1200 65 1.10 2.02 2.50 2.29 2.18 1.68 Failure 840 600 Comp.
 9  D 772 1250 63 - 2.43 2.38 2.25 2.08 1.53 Pass 862 500 Ex. Of inv.
 10  1250 63 - 2.42 2.41 2.19 2.07 1.58 Pass 878 500 Ex. Of inv.
 eleven      1230 66 2.21 2.41 2.72 2.52 2.40 1.93 Pass 892 600 Ex. Of inv.
 12  E 869 1200 63 2.04 2.49 2.57 2.02 1.95 1.47 Pass 885 500 Ex. Of inv.
 13      1000 66 2.17 2.55 2.69 2.51 2.42 1.82 Pass 825 500 Comp.
 14  F 730 1170 72 2.23 2.89 3.36 2.82 2.33 2.96 Pass 815 500 Ex. Of inv.
 fifteen  1150 76 2.11 2.56 3.09 2.87 2.57 1.91 Pass 792 600 Alloy Ex.
 16      1075 75 2.37 2.95 3.88 3.86 3.35 3.37 Pass 892 500 Ex. Of inv.
 17  G 771 1200 70 2.10 2.70 3.18 2.58 2.44 1.92 Pass 863 550 Ex. Of inv.
 18      1250 69 - - - 2.55 2.42 2.07 Pass 935 650 Comp.
 19  H 688 1230 74 2.34 2.99 3.77 3.95 3.61 2.87 Pass 882 650 Ex. Of inv.
 twenty  1250 31 - - 1.65 1.73 1.89 2.32 Failure 893 550 Comp.
 twenty-one    727 1200 68 2.12 2.46 2.76 2.55 2.09 2.02 Pass 861 350 Inv.
 22  I 1150 62 2.01 2.41 2.41 2.21 2.10 1.49 Pass 823 500 Ex. Of inv.
 2. 3  J 718 1170 76 2.44 3.13 4.09 4.44 4.65 3.66 Pass 829 550 Ex. Of inv.
 24  1250 63 - - - 2.19 2.08 1.49 Failure 892 550 Comp.


 Product No.  Steel Ar3 SRT Form Ratio FT CT Plating Remarks
 ° C ° C  Lamination% 1P 2P 3P 4P 5P 6P Pass / Fail  ° C ° C
 25      1230 64 2.03 2.43 2.51 2.38 2.37 1.58 Pass 887 500 Ex. Of inv.
 26  K 777 1200 66 2.07 2.50 2.65 2.61 2.46 1.90 Pass 853 550 Hot dip Ex. Of inv.
 27      1250 70 - - 2.30 2.10 2.20 2.54 Pass 898 750. Eg comp
 28      1170 65 2.11 2.60 2.53 2.37 2.33 1.64 Pass 821 500 Ex. Of inv.
 29  L 729 1150 76 2.49 3.17 4.45 4.53 4.62 3.83 Pass 795 550 Alloy. Ex. Of the inv.
 30      1270 77 - - 4.16 4.74 4.85 3.66 Pass 885 350 Inv.
 31  M 775 1230 79 2.81 3.70 4.61 5.57 6.40 5.85 Pass 873 500 Ex. Of inv.
 32  1200 50 1.95 2.44 2.30 2.08 1.87 1.35 Pass 861 600. Ex. Of the inv.
 33      1200 73 2.38 2.94 3.60 3.76 3.91 3.19 Pass 864 550 Ex. Of inv.
 3. 4  N 707 1250 76 - 3.07 4.03 4.40 4.79 3.66 Pass 897 650 Inv.
 35      1150 25 1.92 2.30 2.20 1.98 1.89 1.50 Failure 805 500 Comp.
 36  O 765 1200 74 2.29 2.90 3.88 3.93 3.88 2.80 Pass 862 550 Ex. Of inv.
 37  P 720 1130 65 2.02 2.53 2.40 2.20 2.14 1.67 Pass 826 500 Ex. Of inv.
 38  1230 77 2.57 3.31 4.45 4.48 4.80 3.68 Pass 895 500 Ex. Of inv.
 39  Q 739 1200 77 2.57 3.29 4.57 4.99 5.18 4.27 Pass 862 650 Inv.
 40  R 721 1250 79 2.57 3.43 4.98 5.12 5.75 4.74 Pass 889 550 Ex. Of inv.
 41  S 727 1150 61 2.32 2.65 3.49 3.53 3.50 1.89 Pass 865 550 Ex. Of inv.
 42  T 745 1250 44 1.57 1.23 2.31 1.89 2.50 2.62 Pass 850 600 Ex. Of inv.
 43  U 759 1250 79 2.48 3.36 4.82 5.42 5.68 4.95 Pass 895 550 Comp.
 44  V 935 1170 77 2.51 3.45 4.59 5.13 4.96 3.71 Pass 830 550 Comp.
 Four. Five  w 800 1200 74 2.34 2.99 3.90 3.84 3.81 2.87 Pass 845 500 Comp.
 46  X 678 1150 43 1.42 1.85 2.30 2.25 1.98 1.79 Failure 825 550 Comp.
 47  And 746 1250 77 2.33 3.06 4.23 4.39 4.45 3.72 Pass 850 650 Comp.
 48  z 757 1170 74 2.18 2.75 3.57 3.57 3.52 2.63 Pass 809 450 Comp.


 Product No.  Steel TS MPa Texture of part 1/6 of sheet thickness Texture of part 1/2 of sheet thickness Static Young Module Dynamic Young Module Remarks
 one*  2 * {332} <113> (A) {225} <110> (B) (A) / (B) RD GPa TD GPa RD GPa TD GPa
 one  A 415 2.7 6.2 4.2 6.5 0.65 225 228 231 232 Ex.
 2  425 0.0 9.3 4.5 6.9 0.65 228 235 230 235 Ex.
 3  430 0.8 8.4 5.2 7.3 0.71 227 231 232 234 Ex.
 4  B 576 1.8 6.4 5.0 6.6 0.76 225 229 233 233 Ex.
 5  623 2.5 3J) 4.9 5.88 0.84 206 216 216 223 Comp.
 6  C 782 0.3 11.1 8.2 10.2 0.80 231 235 235 233 Ex. Of inv.
 7  723 1.7 7.0 7.6 8.3 0.92 225 231 231 236 Ex. Of Inv.
 8  689 0.8 4J3 4.5 6.2 0.73 214 223 232 230 Comp.
 9  D 545 1.9 8.4 4.6 8.3 0.55 226 228 231 231 Ex. Of Inv.
 10  535 2.1 6.0 4.0 8.9 0.45 224 229 230 235 Ex. Of inv.
 eleven  E 555 3.4 5.5 5.6 9.2 0.61 223 230 229 236 Ex.
 12  592 3.5 6.5 4.2 8.8 0.48 223 228 230 234 Ex.
 13  620 L5 6.3 4.2 7.5 0.56 215 239 215 238 Comp.
 14  F 580 0.0 10.4 6.2 8.7 0.71 231 236 237 234 Ex. Of inv.
 fifteen  544 0.0 12.6 7.2 9.3 0.77 233 234 240 236 Ex. Of the inv.
 16  G 758 3.2 5.7 6.2 7.9 0.78 223 226 231 234 Ex. Of Inv.
 17  792 1.8 7.0 6.2 8.3 0.75 226 224 233 231 Ex. Of the inv.
 18  725 0.0 12 5.2 5.2 1.00 206 215 216 223 Comp.
 19  H 601 0.2 7.4 4.3 8.6 0.50 226 231 231 231 Ex. Of inv.
 twenty  645 1.8 2J3 3.2 3.5 0.91 210 216 222 227 Comp.
 twenty-one  I 620 1.2 8.6 7.8 9.6 0.81 228 234 235 233 Ex. Of inv.
 22  582 0.0 11.2 7.3 9.4 0.78 230 231 239 233 Ex. Of the inv.
 2. 3  J 589 0.0 11.1 4.6 11.2 0.41 230 233 234 236 Ex. Of inv.
 24  599 0.0 13 9.3 7.8 1.19 216 235 231 235 Comp.
(Note): Underlines are conditions outside the range of the present invention
1 *: Sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and the ratio of random intensity of X-rays in the orientation of {110} <001>
2 *: Sum of the maximum value of the ratios of random intensity of X-rays in the orientation group of {110} <111> and the ratio of random intensity of X-rays in the orientation of {211} <111>


 Product No.  Steel TS MPa Texture of part 1/6 of sheet thickness Texture of part 1/2 of sheet thickness Static Young Module Dynamic Young Module Remarks
 one*  2 * {332} <113> (A) {225} <110> (B) (A) / (B) RD GPa TD GPa RD GPa TD GPa
 25  K 613 3.9 6.0 4.6 7.8 0.59 225 231 231 233 Ex. Of Inv.
 26  629 1.1 8.5 5.3 8.2 0.65 226 236 235 232 Ex.
 27  576 0.0 OJi 4.6 4.6 1.00 213 229 228 234. Eg comp.
 28  L 653 0.0 11.0 6.5 8.2 0.79 230 233 238 231 Ex.
 29  659 0.0 11.5 5.9 7.7 0.77 234 236 238 234 Ex. Of the inv.
 30  689 1.1 5.7 6.9 8.3 0.83 224 236 231 230 Ex.
 31  M 690 4.0 5.8.5 9.2 0.92 222 239 233 241 Ex. Of inv.
 32  699 2.1 6.3 10.5 11.5 0.91 223 234 235 236 Ex.
 33  N 735 1.1 8.4 16.0 5.78 2.76 225 231 242 233 Ex. Of inv.
 3. 4  632 1.7 6.8 11.5 8.3 1.39 223 230 241 235 Ex.
 35  752 0.0 O0 2.6 3.2 0.81 204 216 204 220 Comp.
 36  O 650 1.3 9.0 7.6 8.2 0.93 227 231 232 231 Ex. Of inv.
 37  P 662 0.9 14.4 7.9 10.6 0.75 234 231 239 234 Ex.
 38  689 1.4 7.4 6.5 8.6 0.76 225 236 231 234 Ex.
 39  Q 660 1.4 9.0 8.2 9.6 0.85 227 235 232 236. Ex. Of the inv.
 40  R 980 1.2 7.4 9.5 10.5 0.90 223 234 237 237 Ex.
 41  S 594 4.3 5.9 6.9 8.3 0.83 222 235 229 237 Ex.
 42  T 792 2.3 6.0 4.6 12.5 0.37 223 235 230 235 Ex. Of inv.
 43  U 708 5J_ 4J3 6.1 5.5 1.11 213 231 231 235 Comp.
 44  V 442 4.3 2J3 1.2 8.3 0.14 209 230 221 232 Comp.
 Four. Five  w 523 9J2 6.1 7.6 10.3 0.74 216 231 237 232 Comp.
 46  X 728 3.9 3J3 5.3 7.8 0.68 215 228 220 233 Comp.
 47  Y 542 2.2 22. 4.5 5.7 0.79 203 229 205 230 Comp.
 48  z 555 4.3 22 3.6 6.2 0.58 206 216 205 217 Comp.
(Note): Underlines are conditions outside the range of the present invention
1 *: Sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and the ratio of random intensity of X-rays in the orientation of {110} <001>
2 *: Sum of the maximum value of the ratios of random intensity of X-rays in the orientation group of {110} <111> and the ratio of random intensity of X-rays in the orientation of {211} <111>


The steels C and M shown in Table 1 were used for hot rolling under the conditions shown in Table 6. Production numbers 50, 52, and 53 shown in Table 6 are examples of peripheral speed rolling differential that change the peripheral velocity rates differential in the three finishing passes of 5 the finishing rolling box comprising a total of six passes, that is, the fourth pass, fifth pass, and sixth pass. Note that the hot rolling conditions not shown in Table 6 are similar to Example 1. In addition, in the same manner as in Example 1, tensile properties and textures of the part corresponding to 1/6 of the thickness of the sheet and the part corresponding to A of the thickness of the sheet and Young's modulus was measured. The results are shown in Table 7.
10 As is clear from this, when the hot rolling steel containing the chemical ingredients of the present invention in suitable conditions, in case of applying 1% or more of rolling with differential peripheral speed for one pass or more, the formation of Texture near the surface layer is promoted and in addition Young's modulus is improved.
 Product No.  Steel Ar3 SRT Form Ratio Rate Differential peripheral speed rate% FT CT Remarks
 ° C ° C  lamination% 1P 2P 3P 4P 5P 6P Pass / fail 4th pass 5th pass 6th pass  ° C ° C
 49  C 747 1250 80 - 3.57 5.23 5.92 6.11 5.23 Pass 0 0 0 885 500 Ex.
 fifty  78 2.52 3.57 5.22 5.93 5.00 5.23 Pass 10 5 5 889 500 Ex. Of inv.
 51        52 1.95 2.44 2.30 2.20 1.87 2.40 Pass 0 0 0 861 600 Ex. Of inv.
 52  M 775 1200 53 1.95 2.44 2.30 2.18 1.92 2.40 Pass 3 3 3 859 600 Ex. Of inv.
 53        55 1.95 2.44 2.30 2.25 1.93 2.35 Pass 0 20 20 855 600 Ex. Of inv.
Table 7
 Product No.  Steel TS MPa Texture of part 1/6 of sheet thickness Texture of part 1/2 of sheet thickness Static Young Module Dynamic Young Module Remarks
 one*  2 * {332} <113> (A) {225} <110> (B) (A) / (B) RD GPa TD GPa RD GPa TD GPa
 49  C 723 1.7 8.0 7.6 8.3 0.92 225 231 231 236 Ex. Of Inv.
 fifty  735 1.1 13.8 7.3 8.5 0.86 236 236 239 237 Ex.
 51  M 699 2.1 7.3 7.9 9.2 0.86 223 234 235 236 Ex.
 52  712 1.6 9.2 6.5 7.2 0.9 232 237 238 239 Ex.
 53  708 0.9 12.5 5.8 8.0 0.7 236 241 240 241 Ex. Of inv.
1 *: Sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and the ratio of random intensity of X-rays in the orientation of {110} <001>
2 *: Sum of the maximum value of the ratios of random intensity of X-rays in the orientation group of {110} <111> and the ratio of random intensity of X-rays in the orientation of {211} <111>


The steels D and N shown in Table 1 were used for hot rolling while changing the effective deformation £ * as shown in Table 8. Note that the hot rolling conditions not shown in the Table 8 are similar to Example 1. In addition, in the same manner as in Example 1, the tensile properties and textures of the part corresponding to 1/6 of the thickness of the sheet and the part corresponding to A of the thickness were measured of the sheet and Young's modulus was measured. The results are shown in Table 9.
As is clear from this, when the hot rolling steel containing the chemical ingredients of the present invention under suitable conditions, in case the effective deformation £ * is set at 0.4 or more, the texture formation near The surface layer is promoted and the Young's module is also improved.
 Product No.  Steel Ar3 SRT Form Ratio FT CT Plating Remarks
 ° C ° C  Lamination% 1P 2P 3P 4P 5P 6P Pass / Fail ° C  ° C
 54      1250 88 2.37 3.57 4.09 3.95 4.52 5.23 Pass 862 0.52 500 Inv.
 55  D 772 1150 89 2.35 3.56 4.11 3.85 4.59 5.25 Pass 852 0.58 500 Ex. Of Inv.
 56      1150 88 2.37 3.56 4.10 3.91 4.52 5.26 Pass 858 0.72 500 Ex. Of inv.
 57      1200 84 3.00 3.08 4.15 3.88 4.17 3.29 Pass 864 0.58 550 Ex. Of inv.
 58  N 707 1200 85 3.00 3.08 4.15 3.88 4.17 3.29 Pass 857 0.65 500 Ex. Of inv.
 59      1150 84 3.00 3.09 4.15 3.88 4.17 3.29 Pass 862 0.75 500 Ex. Of inv.
Table 9
 Product No.  Steel TS MPa Texture of part 1/6 of sheet thickness Texture of part 1/2 of sheet thickness Static Young Module Dynamic Young Module Remarks
 one*  2 * {332} <113> (A) {225} <110> (B) (A) / (B) RD GPa TD GPa RD GPa TD GPa
 54  D 560 0.0 8.4 4.3 8.1 0.53 222 231 235 230 Ex. Of inv.
 55  555 0.0 9.2 4.0 8.9 0.45 224 232 236 230 Ex.
 56  562 0.0 9.8 4.0 9.3 0.43 225 232 238 233 Ex. Of the inv.
 57  N 546 1.3 9.2 4.6 8.3 0.55 223 234 236 235 Ex.
 58  546 1.5 9.6 4.0 8.9 0.45 225 235 236 235 Ex. Of the inv.
 59  552 0.0 10.2 4.2 9.5 0.44 227 236 238 236 Ex.
1 *: Sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and the ratio of random intensity of X-rays in the orientation of {110} <001>
2 *: Sum of the maximum value of the ratios of random intensity of X-rays in the orientation group of {110} <111> and the ratio of random intensity of X-rays in the orientation of {211} <111>


5
10
fifteen
twenty
25
30
35
The steel containing the composition shown in Table 10 (rest of Fe and unavoidable impurities) was produced to produce a steel slab. The steel slab was heated, approximately hot rolled, then a finishing lamination was carried out under the conditions shown in Table 11. The finishing laminator box consists of six passes in total. The diameter of the roller was 700 to 830 mm. In addition, the thickness of the finished strap after the finishing pass was set at 1.6 mm to 10 mm. The "-" of the column of formula 1 means a comparative example in which Ti is not added.
From the steel sheet obtained, in the same manner as in Example 1, the tensile strength and Young's modulus were measured and the texture of the part corresponding to 1/6 thickness of the sheet sheet was measured. of steel. In addition, the ratios of random intensity of X-rays in the orientation of {332} <113>, the orientation of {001} <110> and the orientation of {112} <110> of the part corresponding to A of the thickness of the sheet of the steel sheet, in the same way as the sample of the part corresponding to 1/6 of the thickness of the sheet, were found from the FDO by X-ray diffraction using adjusted samples so that the part corresponding to A thickness of the sheet became the measuring surface. Among these steel sheets, hot dipped galvanized after the end of hot rolling was indicated as "hot dipping", and those hot dipped galvanized and annealed at 520 ° C for 15 seconds are indicated as "alloy "
The results are shown in Table 12. As is clear from Table 12, when the hot rolling steel contains the chemical ingredients of the present invention under suitable conditions, it was possible to establish that the Young's modulus by the static tension method be greater than 220 GPa, both in the rolling direction and in the orientation perpendicular to the lamination. In particular, it is known that when the conditions of the texture of the central layer of the sheet thickness are met simultaneously, Young's modulus by the static tension method is high and the difference with the vibration method is reduced.
On the other hand, production number 78 is an example using AL steel with a small amount of Mn. Ar3 rises. As a result, hot rolling is performed at Ar3 or less, the orientation concentration of {110} <001> is raised, and Young's modulus in the rolling direction decreases. In addition, production no. 79 and 80 are examples that do not contain AO steel and do not comply with formula 1 and AP steel that do not contain Nb. The sum of the relations of random intensity of X-rays in the orientation group of {110} <111> to {110} <112> and the ratio of random intensity of X-rays in the orientation of {211} <111> of the corresponding part 1/6 of the thickness of the sheet decreases and Young's modulus in the rolling direction decreases.
In addition, as shown in the comparative examples of steels AA, AC, and AE, that is, production numbers 61, 64, and 67, in case of a number of passes, where the shape relationship is 2.3 or more, it is small, even if a high Young's modulus is obtained by the vibration method, 220 GPa cannot be overcome by the static tension method. In addition, as shown in the comparative example of AG steel, that is, production number 70, in case of a number of passes, where the shape ratio is 2.3 or more, it is small and the speed Lamination is low, Young's modules by the vibration method and the static tension method decrease below 220 GPa.
 Ingredients (% by mass) Form 1 Form 2 Ar3 ° C Remarks
 C  Yes Mn P S Al N Nb Ti B Cr W Cu Ni Mo Ca, V, Rem
 AA  0.052 0.61 1.68 0.007 0.0049 0.058 0.0018 0.034 0.032 0.0015 0.04 0.16 0.026 6.94 737 Ex.
 AB  0.049 0.01 1.22 0.009 0.0048 0.036 0.0027 0.013 0.023 0.0017 0.03 0.04 0.014 4.67 772
 AC  0.034 0.01 1.62 0.010 0.0011 0.033 0.0020 0.043 0.035 0.0024 0.06 0.01 Ca: 0.0006 0.028 6.36 739
 AD  0.072 0.33 1.80 0.013 0.0041 0.041 0.0016 0.021 0.028 0.0009 0.02 0.31 0.023 7.23 727
 AE  0.043 0.01 1.70 0.009 0.0038 0.035 0.0021 0.032 0.019 0.0023 0.02 0.01 0.20 0.012 7.79 714
 AF  0.050 0.01 1.20 0.013 0.0030 0.043 0.0022 0.035 0.017 0.0035 0.28 0.14 0.009 9.92 748
 AG  0.031 0.34 1.83 0.041 0.0052 0.040 0.0025 0.037 0.026 0.0026 0.07 0.03 0.22 Rem: 0.001 0.017 9.46 719
 AH  0.118 0.58 1.78 0.012 0.0043 0.034 0.0037 0.029 0.034 0.0008 0.05 0.03 V: 0.022 0.021 6.29 718
 To the  0.145 1.21 1.38 0.011 0.0032 0.061 0.0026 0.034 0.041 0.0013 0.45 0.18 0.07 0.032 6.25 745
 AJ  0.041 1.63 2.10 0.016 0.0039 0.035 0.0020 0.027 0.026 0.0014 0.04 0.25 0.019 9.15 729
 AK  0.111 0.01 1.42 0.012 0.0042 0.037 0.0025 0.032 0.037 0.19 0.11 0.028 8.76 717
 TO THE  0.041 0.12 0.80 0.008 0.0021 0.032 0.0019 0.023 0.020 0.0011 0.02 0.013 2.57 821
 A.M  0.044 0.08 2.95 0.010 0.0033 0.035 0.0018 0.018 0.015 0.0022 0.03 0.10 0.50 0.35 0.009 17.78 556
 AN  0.040 1.60 0.08 0.012 0.0050 0.040 0.0020 0.030 0.015 0.0020 0.02 0.01 0.03 0.008 0.64 935 Comp.
 AO  0.062 0.01 1.36 0.032 0.0051 0.033 0.0021 0.036 - 4.35 767
 AP  0.081 0.60 1.48 0.007 0.0033 0.028 0.0023 0.024 0.03 0.02 V: 0.007 0.016 5.13 758
(Note) Underlines are conditions outside the range of the present invention
Formula 1: Ti-48 / 14xN
Formula 2: 3.2Mn + 9.6Mo + 4.7W + 6.2Ni + 18.6Cu + 0.7Cr


 Product No.  Steel Ar3 SRT Form Ratio FT CT Coating Remarks
 ° C ° C  Lamination% 1P 2P 3P 4P 5P 6P Pass / Fail  ° C ° C
 60  AA 737 1200 76 2.32 2.93 4.19 4.12 4.19 3.51 Pass 816 450 Hot dip Ex. Of inv.
 61  1200 65 1.10 2.02 2.50 2.29 2.18 1.68 Failure 841 600 Comp.
 62  AB 772 1250 63 - 2.43 2.38 2.25 2.08 1.53 Pass 860 500 Ex. Of inv.
 63  AC 739 1230 74 2.34 2.99 3.77 3.95 3.61 2.87 Pass 881 650 Alloy Ex.
 64  1250 31 - - 1.64 1.73 1.89 2.32 Failure 894 550 Comp.
 65  AD 727 1200 68 2.12 2.46 2.76 2.55 2.09 2.02 Pass 860 350 Alloy Ex.
 66  AE 714 1170 76 - 3.13 4.09 4.44 4.65 3.66 Pass 826 550 Ex. Of inv.
 67  1250 63 2.44 - - 2.19 2.08 1.49 Failure 890 550 Comp.
 68  AF 748 1230 79 -2.81 3.70 4.61 5.57 6.40 5.85 Pass 872 500 Ex. Of inv.
 69  AG 719 1200 73 2.38 2.94 3.60 3.76 3.91 3.19 Pass 865 550 Ex. Of inv.
 70  1150 25 1.92 2.30 2.20 1.98 1.89 1.50 Failure 804 500 Comp.
 71  AH 718 1130 65 2.02 2.53 2.40 2.20 2.14 1.67 Pass 823 500 Hot dip Ex. Of inv.
 72  1230 77 2.57 3.31 4.45 4.48 4.80 3.68 Pass 896 500 Ex. Of inv.
 73  At 745 1200 77 2.57 3.29 4.57 4.99 5.18 4.27 Pass 860 650 Ex. Of Inv.
 74  AJ 729 1250 79 2.57 3.43 4.98 5.12 5.75 4.74 Pass 888 550 Ex. Of inv.
 75  AK 717 1150 61 2.32 2.65 3.49 3.53 3.50 2.89 Pass 867 550 Ex. Of Inv.
 76  AL 822 1170 77 2.51 3.42 4.49 5.23 5.01 3.65 Pass 852 550 Ex. Of inv.
 77  AM 533 1250 69 2.23 3.45 4.42 4.39 4.63 3.71 Pass 803 550 Ex. Of inv.
 78  AN 935 1170 77 2.51 3.45 4.59 5.13 4.96 3.71 Pass 830 550 Comp.
 79  AO 767 1200 74 2.34 2.99 3.90 3.84 3.81 2.87 Pass 843 500 Comp.
 80  AP 758 1170 74 2.18 2.75 3.57 3.57 3.52 2.63 Pass 810 450 Comp.
(Note) Underlines are conditions outside the range of the present invention


 Product No.  Steel TS MPa Texture of part 1/6 of sheet thickness Texture of part 1/2 of sheet thickness Static Young Module Dynamic Young Module Remarks
 one*  2 * (A) (C) (A) / (C) RD GPa TD GPa RD GPa TD GPa
 60  AA 781 0.4 10.9 8.1 10.1 0.80 232 234 234 231 Ex. Of the inv.
 61  688 0.8 4J5 4.6 6.3 0.73 212 221 231 229 Comp.
 62  AB 546 2.0 8.3 4.6 8.2 0.56 227 225 230 230 Ex.
 63  AC 600 0.2 7.4 4.3 8.6 0.50 225 232 230 230 Ex.
 64  646 1.9 2J_ 3.1 3.6 0.86 211 215 221 226 Comp.
 65  AD 651 1.2 8.6 7.7 9.6 0.80 226 232 234 232 Ex.
 66  AE 588 0.0 11.1 4.5 11.0 0.41 230 231 235 235 Ex. Of inv.
 67  590 0.1 13 9.1 7.5 1.21 215 234 230 236 Comp.
 68  AF 692 3.9 5.8 8.6 9.2 0.93 225 238 234 240 Ex.
 69  AG 737 1.0 8.3 8.4 7.7 1.09 226 230 241 231 Ex.
 70  748 0.0 O0 2.7 3.3 0.82 202 215 206 219 Comp.
 71  AH 663 1.0 14.5 8.0 10.5 0.76 235 230 237 231 Ex.
 72  692 1.3 7.5 6.7 8.5 0.79 225 235 232 232 Ex.
 73  At 657 1.5 9.1 8.0 9.5 0.84 226 236 231 235 Ex. Of the inv.
 74  AJ 981 1.1 7.3 9.3 10.3 0.90 228 233 236 236 Ex. Of the inv.
 75  AK 595 4.4 12.5 7.0 8.1 0.86 229 236 230 235 Ex.
 76  AL 548 2.8 5.1 3.4 4.6 0.74 221 229 231 234 Ex. Of Inv.
 77  AM 1128 0.0 14.7 15.2 11.3 1.35 220 238 245 242 Ex. Of inv.
 78  AN 442 L2 5.9 1.2 8.3 0.14 209 230 221 232 Comp.
 79  AO 521 4J3 2J5 7.3 10.5 0.70 214 232 235 231 Comp.
 80  AP 554 4J. 2J3 3.5 6.1 0.57 205 215 206 215 Comp.
(Note): Underlines are conditions outside the range of the present invention
1 *: Sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and the ratio of random intensity of X-rays in the orientation of {110} <001>
2 *: Sum of the maximum value of the ratios of random intensity of X-rays in the orientation group of {110} <111> and the ratio of random intensity of X-rays in the orientation of {211} <111>
(A): Ratio of random intensity of X-rays in the orientation of {332} <113>
(C): Average value of the ratios of random intensity of X-rays in the orientation of {211} <110> and {100} <110>


The steels AA and AF shown in Table 10 were used for hot rolling under the conditions shown in Table 13. Production numbers 82, 84 and 85 shown in Table 13 are examples of speed rolling differential peripheral that change the differential peripheral velocity rates in the three passes of 5 finishing of the finishing laminator box comprising a total of six passes, that is, fourth pass, fifth pass, and sixth pass. Note that the hot rolling conditions not shown in Table 13 are similar to Example 4. In addition, in the same manner as in Example 4, the tensile properties and textures of the part corresponding to 1/6 of the thickness of the sheet and the part corresponding to A of the thickness of the sheet and Young's modulus was measured. The results are shown in Table 14.
As is clear from this, when the hot rolling steel contains the chemical ingredients of the present invention in suitable conditions, in case of applying 1% or more of rolling with differential peripheral speed for one pass or more, the texture formation The Young's module is promoted near the surface layer.
 Product No.  Steel Ar3 ° C SRT ° C Rolling rate% Form ratio Differential peripheral speed rate% I— or LL or CT ° C Plated Remarks
 1 P  2P 3P 4P 5P 6P Pass / fail 4th pass 5th pass 6th pass
 81  AA 737 1250 80 - 3.57 5.23 5.92 6.11 5.23 Pass 0 0 0 886 500 Hot dip Ex. Of inv.
 82  78 2.52 3.57 5.22 5.93 5.00 5.23 Pass 10 5 5 890 500 Ex. Of inv.
 83  AF 748 1200 52 1.95 2.44 2.30 2.20 1.87 2.40 Pass 0 0 0 860 600 Ex. Of inv.
 84  53 1.95 2.44 2.30 2.18 1.92 2.40 Pass 3 3 3 858 600 Alloy Ex.
 85  55 1.95 2.44 2.30 2.25 1.93 2.35 Pass 0 20 20 856 600 Ex. Of inv.
Table 14
 Product No.  Steel TS MPa Texture of the part 1/6 thickness of the sheet Texture of the part 1/2 of the thickness of the sheet Static Young Module Dynamic Young Module Remarks
 one*  2 * (A) (C) (A) / (C) RD GPa TD GPa RD GPa TD GPa
 81  AA 724 1.6 7.9 7.5 8.4 0.89 224 230 231 235 Ex.
 82  734 1.0 13.8 7.2 8.4 0.86 237 235 239 236 Ex.
 83  AF 700 2.2 7.1 8.0 9.1 0.88 222 233 234 236 Ex.
 84  711 1.7 9.1 6.6 7.1 0.93 231 238 237 238 Ex.
 85  709 0.8 12.6 5.7 7.9 0.72 235 240 239 240 Ex. Of inv.
1 *: Sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and the ratio of random intensity of X-rays in the orientation of {110} <001>
2 *: Sum of the maximum value of the ratios of random intensity of X-rays in the orientation group of {110} <111> and the ratio of random intensity of X-rays in the orientation of {211} <111>
(A): Ratio of random intensity of X-rays in the orientation of {332} <113>
(C): Average value of the ratios of random intensity of X-rays in the orientation of {211} <110> and {100} <110>


The steels AB and AG shown in Table 10 were used for hot rolling while changing the effective deformations £ * as shown in Table 15. Note that the hot rolling conditions not shown in the Table 15 are similar to Example 4. In addition, in the same manner as in Example 4, the tensile properties and textures of the part corresponding to 1/6 of the thickness of the sheet and the part corresponding to A of the thickness were measured of the sheet and Young's modulus was measured. The results are shown in Table 16.
As is clear from this, when the hot rolling steel contains the chemical ingredients of the present invention in suitable conditions, in case the effective deformation £ * is set at 0.4 or more, the texture formation near the surface layer is promoted and also Young's module is improved.
 Product No.  Steel Ar3 SRT Form Ratio FT CT Plating Remarks
 ° C ° C  Lamination% 1P 2P 3P 4P 5P 6P Pass / Fail ° C £  ° C
 86      1250 88 2.37 3.57 4.09 3.95 4.52 5.23 Pass 861 0.51 500 Ex. Of inv.
 87  AB 772 1150 89 2.35 3.56 4.11 3.85 4.59 5.25 Pass 851 0.57 500 Hot dip Ex. Of inv.
 88      1150 88 2.37 3.56 4.10 3.91 4.52 5.26 Pass 859 0.73 500 Ex. Of inv.
 89      1200 84 3.00 3.08 4.15 3.88 4.17 3.29 Pass 863 0.59 550 Ex. Of inv.
 90  AG 719 1200 85 3.00 3.08 4.15 3.88 4.17 3.29 Pass 858 0.64 500 Alloy Ex.
 91      1150 84 3.00 3.08 4.15 3.88 4.17 2.39 Pass 863 0.76 500 Ex. Of inv.
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Table 16
 Product No.  Steel TS MPa Texture of part 1/6 of sheet thickness Texture of part 1/2 of sheet thickness Static Young Module Dynamic Young Module Remarks
 one*  2 * (A) (C) (A) / (C) RD GPa TD GPa RD GPa TD GPa
 86  AB 561 0.0 8.5 4.2 8.0 0.53 221 230 234 229 Ex. Of inv.
 87  556 0.0 9.3 3.9 8.8 0.44 223 231 235 231 Ex. Of Inv.
 88  561 0.0 9.9 3.9 9.4 0.41 226 231 239 231 Ex. Of the inv.
 89  AG 548 1.2 9.1 4.5 9.2 0.55 222 233 235 233 Ex. Of Inv.
 90  545 1.4 9.7 4.1 9.0 0.45 224 234 237 234 Ex.
 91  551 0.0 10.1 4.2 9.3 0.45 228 235 239 237 Ex.
1 *: Sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and the ratio of random intensity of X-rays in the orientation of {110} <001>
2 *: Sum of the maximum value of the ratios of random intensity of X-rays in the orientation group of {110} <111> and the ratio of random intensity of X-rays in the orientation of {211} <111>
(A): Ratio of random intensity of X-rays in the orientation of {332} <113>
(C): Average value of the ratios of random intensity of X-rays in the orientation of {211} <110> and {100} <110>


Industrial applicability
Young's high modulus steel sheet of the present invention is used for automobiles, household electrical devices, building materials, etc. In addition, the Young high modulus steel sheet of the present invention includes the hot rolled steel sheet in the strict sense that is not subjected to surface treatment, as well as the hot rolled steel sheet in the broad sense that It is subjected to surface treatment, such as hot dip galvanization, hot dip galvanizing and electroplating and electroplating, in order to prevent oxidation. The surface treatment includes aluminum based plating, formation of organic coatings and inorganic coatings on the surfaces of the hot rolled steel sheet and various types of plated steel sheet, and combinations thereof.
The steel sheet of the present invention has a high Young's modulus, so it is possible to reduce its sheet thickness compared to a conventional steel sheet, that is, it is possible to lighten the weight and contribute to the protection of the global environment In addition, the steel sheet of the present invention also has an improved ability to fix the shape, so that the application of the high strength steel sheet for automobile components and other parts under pressure can be easily adopted. In addition, a
The component obtained by conformation and workability of the steel sheet of the present invention is superior in the characteristic of impact energy absorption, so it also contributed to improving the safety of automobiles.
5
10
fifteen
twenty
25
30
35
40

1. Steel sheet with high Young's modulus that has a longitudinal Young's modulus measured by the static tension method of 220 GPa or more, consisting, in mass%, in
C: 0.005 to 0.200%,
If: 2.50% or less,
Mn: 0.10 to 3.00%,
P: 0,150% or less,
S: 0.0150% or less,
At: 0.010 to 0.150%,
N: 0.0005 to 0.0100%,
Nb: 0.005 to 0.100%, and
Ti: 0.002 to 0.150%, optionally one or more of Mo: 0.01 to 1.00%,
Cr: 0.01 to 3.00%,
W: 0.01 to 3.00%,
Cu: 0.01 to 3.00%,
Ni: 0.01 to 3.00%,
B: 0.0005 to 0.0100%,
Ca: 0.0005 to 0.1000%,
Rem: 0.0005 to 0.1000%, and V: 0.001 to 0.100%
complies with formula 1, has a remainder of Fe and unavoidable impurities, has a sum of the ratio of random intensity of X-rays in the orientation of {100} <001> and a ratio of random intensity of X-rays in the orientation of {110} <001> of 5 or less in a position of one direction of the surface of the steel sheet in the direction of the thickness of the sheet corresponding to 1/6 of the thickness of the sheet, and has a sum of a value maximum of the X-ray random intensity ratios in the orientation group of {110} <111> to {110} <112> and a random X-ray intensity ratio in the orientation of {211} <111> of 5 or more:
Ti-48/14 * N> 0.0005 ... formula 1
where, Ti and N are the contents (mass%) of the elements.
2. A steel sheet with Young's high modulus as set forth in claim 1, characterized by complying with the following formula 2:
4 <3.2Mn + 9.6Mo + 4.7W + 6.2Ni + 18.6Cu + 0.7Cr <10 ... formula 2
where, Mn, Mo, W, Ni, Cu and Cr are the contents (mass%) of the elements.
3. A Young high modulus steel sheet according to claim 1 or 2, characterized by having a random intensity ratio of X-rays in the orientation of {332} <113> (A) of 15 or less and a ratio of random intensity of X-rays in the orientation of {225} <110> (B) of 5 or more in a central part of the steel sheet in the direction of the thickness of the sheet and to comply with (A) / (B) <1.00.
4. A sheet of steel with Young's high modulus according to any one of claims 1 to 3, characterized by having a ratio of random intensity of X-rays in the orientation of {332} <113> (A) of 15 or less and a simple average of the ratio of random intensity of X-rays in the orientation of {001} <110> and a ratio of random intensity of X-rays in the orientation of {112} <110> (C) of 5 or more in one central part of the steel sheet in the direction of the thickness of the sheet and to be fulfilled (A) / (C) <1.10.
10
fifteen
twenty
25
5. A steel sheet with a high Young's modulus according to any one of claims 1 to 4, characterized by having a Young's modulus in the rolling direction measured by the static tension method of 220 GPa or more.
6. A hot dipped galvanized steel sheet characterized in that it comprises a Young high modulus steel sheet according to any one of claims 1 to 5 which is hot dipped galvanized.
7. A hot dipped galvanized and annealed steel sheet characterized in that it comprises a Young high modulus steel sheet according to any one of claims 1 to 5, which is galvanized and hot dipped annealed.
8. A method of producing a sheet of steel with a high Young's modulus that has a longitudinal Young's modulus measured by the static tension method of 220 GPa or more, characterized by lamination of a steel slab containing the chemical ingredients according to claims 1 or 2 at 1,100 ° C or less for a rolling rate up to the final pass of 40% or more and for a ratio of form X found by the following formula 3 of 2.3 or more by two passes or more, hot rolling at a final pass temperature of the Ar3 transformation point at 900 ° C, and winding at 700 ° C or less:
Form ratio X = ld / hm ... formula 3
where, ld (contact arc length between the rolling rollers and the steel sheet):
V (LX (inlet-out) / 2)
hm: (input + output) / 2
L: diameter of the rolling rollers
Inlet: sheet thickness of the inlet side of the rolling roller
Output: sheet thickness of the exit side of the rolling roller
9. A method of producing a Young high modulus steel sheet according to claim 8, characterized by hot rolling so that the effective deformation £ * calculated by the following formula 5 becomes 0.4 or more:
image5
where, n is a number of laminator boxes of a final hot rolling mill, £ j is a deformation given in the box, £ n is a deformation given in one nth box, ti is a travel time between ai ai + 1st boxes, and Ti is calculated by the following formula 6 by means of a constant of the gases R (= 1,987) and a rolling temperature Ti (K) of a box:
image6
10. A method of producing a Young high modulus steel sheet according to claim 8 or 9, characterized by carrying out a differential peripheral speed rate of at least one hot rolling pass of 1% or more.
35 11. A method of producing a Young high modulus steel sheet, characterized by galvanization
by hot dipping a steel sheet surface produced by the method according to any of claims 8 to 10.
12. A method of producing a hot-dip galvanized steel sheet, characterized by hot-dip galvanizing a surface of a steel sheet produced by a method according to any one of claims 8 to 10, then heat treating it in a temperature range of 450 to 600 ° C for 10 seconds or more.

权利要求:
Claims (1)
[1]
image 1
image2

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同族专利:

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公开号 | 公开日

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EP2088218B1|2017-09-13|

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CA2668987A1|2008-05-15|

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CA2668987C|2013-04-09|

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BRPI0718542A2|2014-02-04|

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CN101535519A|2009-09-16|

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EP2088218A1|2009-08-12|

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CN101535519B|2012-07-18|

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KR20090086401A|2009-08-12|

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JP2008274395A|2008-11-13|

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PL2088218T3|2018-02-28|

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US8353992B2|2013-01-15|

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EP2088218A4|2013-04-03|

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ES2651242T3|2018-01-25|

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US20100047617A1|2010-02-25|

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WO2008056812A1|2008-05-15|

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KR101109869B1|2012-03-13|

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EP2088218B9|2018-03-14|

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JP5228447B2|2013-07-03|

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BRPI0718542B1|2016-07-19|

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法律状态:

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